Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 1969–1973 | Cite as

Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix

  • E. A. Raiskaya
  • G. G. Saveleva
  • V. A. Drozdov
  • O. B. Belskaya
Production of New Materials
  • 2 Downloads

Abstract

Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (SBET) lower than 5 m2 g–1 at the adsorption capacity for СО2 higher than 1 mmol g–1 for both samples were found.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Pribylov, A.A., Kalinnikova, I.A., and Murdmaa, K.O., Russ. Chem. Bull., 2015, vol. 64, no. 4, pp. 819–824.CrossRefGoogle Scholar
  2. 2.
    P’yanova, L.G., Baklanova, O.N., Drozdov, V.A., et al., Khim. Inter. Ustoich. Razv., 2014, vol. 22, pp. 633–641.Google Scholar
  3. 3.
    Sethupathi S., Bashir M.J.K, Akbar Z.A., et al., Waste Manag. Res., 2015, vol. 33, N 4, pp. 303–312.CrossRefGoogle Scholar
  4. 4.
    Rodrigues S.C., Whitley R., and Mendes, A., J. Membr. Sci., 2014, vol. 459, pp. 207–216.CrossRefGoogle Scholar
  5. 5.
    Thommes, M., Kaneko, K., Neimark, A.V., et al., Pure Appl. Chem., 2015, pp. 1–19.Google Scholar
  6. 6.
    Berveno, A.V. and Berveno, V.P., Polzun. Vestn. (Barnaul), 2009, no. 3, pp. 189–191.Google Scholar
  7. 7.
    Muniandy, L., Adam, F., Mohamed, A.R., and Ng, E.-P., Microp. Mesop. Mater., 2014, vol. 197, pp. 316–323.CrossRefGoogle Scholar
  8. 8.
    Shi, J.-L., Tang, C., Peng, H.-J., et al., Small, 2015, vol. 11, no. 39, pp. 5243–5252.CrossRefGoogle Scholar
  9. 9.
    Minkowycz, W.J., Sparrow, E.M., and Murthy, J.Y., Handbook of Numerical Heat Transfer, Wiley, 2009, p. 984.Google Scholar
  10. 10.
    Garcia-Martinez, J., Gazorla-Amoros, D., and Linares-Solano, A., Studies in Surface Science and Catalysis, Unger, K.K., et al., Eds., Elsevier, 2000, vol. 128, pp. 485–494.Google Scholar
  11. 11.
    Fenelonov, V.B., Vvedenie v fizicheskuyu khimiyu formirovaniya supramolekulyarnoi struktury adsorbentov i katalizatorov (Introduction to Physical Chemistry of Supramolecular Structure Formation in Adsorbents and Catalysts), Novosibirsk: Sibirskoe Otdel. Ross. Akad. Nauk, 2002.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. A. Raiskaya
    • 1
  • G. G. Saveleva
    • 1
  • V. A. Drozdov
    • 1
  • O. B. Belskaya
    • 1
  1. 1.Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia

Personalised recommendations