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Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3–Al2O3 Catalysts

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Abstract

Tungstate-containing aluminum oxide is suitable as a catalyst support for hydrodeoxygenation of sunflower oil, ensuring 81–83 wt % yield of liquid products at 380°С, 4.0 MPa, and feed space velocity of 1 h–1. The catalyst acidity increases with increasing tungsten oxide content, leading to an increase in the content of decarboxylation/decarbonylation products and isoparaffins in the product mixture.

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References

  1. Choudhary, T.V. and Phillips, C.B., Appl. Catal., Ser. A, 2011, vol. 397, no. 1, pp. 1–12.

    CAS  Google Scholar 

  2. Mortensen, P.M., Grunwaldt, J.-D., Jensen, P.A., et al., Appl. Catal., Ser. A, 2011, vol. 407, no. 1, pp. 1–19.

    CAS  Google Scholar 

  3. Zhao, C., Bruck, T., and Lercher, J.A., Green Chem., 2013, vol. 15, no. 7, pp. 1720–1739.

    Article  CAS  Google Scholar 

  4. Bengoechea, M.O., Hertzberg, A., Miletić, N., et al., J. Anal. Appl. Pyrol., 2015, vol. 113, pp. 713–722.

    Article  Google Scholar 

  5. Herskowitz, M., Landau, M.V., Reizner, Y., and Berger, D., Fuel, 2013, vol. 111, pp. 157–164.

    Article  CAS  Google Scholar 

  6. Veriansyah, B., Han, J.Y., Kim, S.K., et al., Fuel, 2012, vol. 94, pp. 578–585.

    Article  CAS  Google Scholar 

  7. De Sousa, F.P., Cardoso, C.C., and Pasa, V.M.D., Fuel Process. Technol., 2016, vol. 143, pp. 35–42.

    Article  Google Scholar 

  8. Kubička, D. and Kaluža, L., Appl. Catal., Ser. A, 2010, vol. 372, no. 2, pp. 199–208.

    Article  Google Scholar 

  9. Besenbacher, F., Bronson, M., and Clausen, B.S., Catal. Today, 2008, vol. 130, pp. 86–96.

    Article  CAS  Google Scholar 

  10. Kubička, D. and Horáček, J., Appl. Catal., Ser. A, 2011, vol. 394, no. 1, pp. 9–17.

    Article  Google Scholar 

  11. Krár, M., Kovács, S., Kalló, D., and Hancsók, J., Bioresource Technol., 2010, vol. 101, no. 23, pp. 9287–9293.

    Article  Google Scholar 

  12. Hancsók, J., Kasza, T., Kovács, S., et al., J. Cleaner Prod., 2012, vol. 34, pp. 76–81.

    Article  Google Scholar 

  13. Kordouli, E., Sygellou, L., Kordulis, C., et al., Appl. Catal., Ser. B, 2017, vol. 209, pp. 12–22.

    Article  CAS  Google Scholar 

  14. Bie, Y., Lehtonen, J., and Kanervo, J., Appl. Catal., Ser. A, 2016, vol. 526, pp. 183–190.

    Article  CAS  Google Scholar 

  15. Gutierrez, A., Turpeinen, E.-M., Viljava, T.-R., and Krause, O., Catal. Today, 2017, vol. 285, pp. 125–134.

    Article  CAS  Google Scholar 

  16. Gusmao, J., Brodzki, D., Djéga-Mariadassou, G., and Frety, R., Catal. Today, 1989, vol. 5, no. 4, pp. 533–544.

    Article  CAS  Google Scholar 

  17. Guzman, A., Torres, J.E., Prada, L.P., and Nunez, M.L., Catal. Today, 2010, vol. 156, nos. 1–2, pp. 38–43.

    Article  CAS  Google Scholar 

  18. Da Rocha Filho, G., Brodzki, D., and Djéga-Mariadassou, G., Fuel, 1993, vol. 72, no. 4, pp. 543–549.

    Article  Google Scholar 

  19. Huber, G.W., O’Connor, P., and Corma, A., Appl. Catal., Ser. A, 2007, vol. 329, no. 1, pp. 120–129.

    Article  CAS  Google Scholar 

  20. Šimáček, P., Kubička, D., Šebor, G., and Pospíšil, M., Fuel, 2009, vol. 88, no. 3, pp. 456–460.

    Article  Google Scholar 

  21. Patent WO 2013050653A1, Publ. 2013.

  22. Patent EP 1 728 844A1, Publ. 2006.

  23. Brillouet, S., Baltag, E., Brunet, S., and Richard, F., Appl. Catal., Ser. B, 2011, vols. 148–149, pp. 201–211.

    Google Scholar 

  24. Wagenhofer, M.F., Barath, E., Gutierrez, O.Y., and Lercher, J.A., ACS Catal., 2017, vol. 7, no. 2, pp.1068−1076.

    Google Scholar 

  25. Şenol, O.I., Ryymin, E.-M., Viljava, T.-R., and Krause, A.O.I., J. Mol. Catal., Ser. A, 2007, vol. 277, nos. 1–2, pp. 107–112.

    Google Scholar 

  26. Coumans, A.E. and Hensen, E.J.M., Appl. Catal., Ser. B, 2017, vol. 201, pp. 290–301.

    Article  CAS  Google Scholar 

  27. Kubička, D., Horáček, J., Setnička, M., et al., Appl. Catal., Ser. B, 2014, vol. 145, pp. 101–107.

    Article  Google Scholar 

  28. Qian, E.W., Chen, N., and Gong, S., J. Mol. Catal., Ser. A, 2014, vol. 387, pp. 76–85.

    Article  CAS  Google Scholar 

  29. Madsen, A.T., Ahmed, E.H., Christensen, C.H., et al., Fuel, 2011, vol. 90, no. 11, pp. 3433–3438.

    Article  CAS  Google Scholar 

  30. Zarchin, R., Rabaev, M., Vidruk-Nehemya, R., et al., Fuel, 2015, vol. 139, pp. 684–691.

    Article  CAS  Google Scholar 

  31. Yang, Y., Wang, Q., Zhang, X., et al., Fuel Process. Technol., 2013, vol. 116, pp. 165–174.

    Article  CAS  Google Scholar 

  32. Sagata, K., Hirose, M., Hirano, Y., and Kita, Y., Appl. Catal., Ser. A, 2016, vol. 523, pp. 85–91.

    Article  CAS  Google Scholar 

  33. Santillan-Jimenez, E., Morgan, T., Lacny, J., et al., Fuel, 2013, vol. 103, pp. 1010–1017.

    Article  CAS  Google Scholar 

  34. Yasir, M., Azizan, M.T., Ramli, A., and Ameen, M., Procedia Eng., 2016, V. 148. P. 275–281.

    Google Scholar 

  35. Mikulec, J., Cvengroš, J., Joríková, L., et al., J. Cleaner Prod., 2010, vol. 18, no. 9, pp. 917–926.

    Article  CAS  Google Scholar 

  36. Mortensen, P.M., de Carvalho, H.W.P., Grunwaldt, J.-D., et al., J. Catal., 2015, vol. 328, pp. 208–215.

    Article  CAS  Google Scholar 

  37. Bui, V.N., Laurenti, D., Delichere, P., and Geantet, C., Appl. Catal., Ser. B, 2011, vol. 101, nos. 3–4, pp. 246–255.

    Article  CAS  Google Scholar 

  38. Duan, J., Han, J., Sun, H., et al., Catal. Commun., 2012, vol. 17, pp. 76–80.

    Article  CAS  Google Scholar 

  39. Kubička, D., Bejblová, M., and Vlk, J., Top. Catal., 2010, vol. 53, pp. 168–178.

    Article  Google Scholar 

  40. Wang, C., Liu, Q., Song, J., et al., Catal. Today, 2014, vol. 234, pp. 153–160.

    Article  CAS  Google Scholar 

  41. Liu, Q., Zuo, H., Zhang, Q., et al., Cuihua Xuebao/Chin. J. Catal., 2014, vol. 35, no. 5, pp. 748–756.

    Article  CAS  Google Scholar 

  42. Chen, N., Gong, S., and Qian, E.W., Appl. Catal., Ser. B, 2015, vols. 174–175, pp. 253–263.

    Article  Google Scholar 

  43. Liu, Q., Zuo, H., Wang, T., et al., Appl. Catal., Ser. A, 2013, vol. 468, pp. 68–74.

    Article  CAS  Google Scholar 

  44. Shahinuzzaman, M., Yaakob, Z., and Ahmed, Y., Renew. Sustain. Energy Rev., 2017, vol. 77, pp. 1375–1384.

    Article  CAS  Google Scholar 

  45. Ishihara, A., Fukui, N., Nasu, H., and Hashimoto, T., Fuel, 2014, vol. 134, pp. 611–617.

    Article  CAS  Google Scholar 

  46. Toba, M., Abe, Y., Kuramochi, H., et al., Catal. Today, 2011, vol. 164, no. 1, pp. 533–537.

    Article  CAS  Google Scholar 

  47. Chumachenko, Yu.A., Lavrenov, A.V., Buluchevskii, E.A., et al., Katal. Prom–sti., 2015, vol. 15, no. 4, pp. 49–64.

    CAS  Google Scholar 

  48. Mohammad, M., Kandaramath Hari, T., and Yaakob, Z., Renew. Sustain. Energy Rev., 2013, vol. 22, pp. 121–132.

    Article  CAS  Google Scholar 

  49. Patent WO 2004022674A1, Publ. 2004.

  50. Patent EP 1396531B2, Publ. 2004.

  51. Tom, N., Kalnes, T., Marker, T., et al., Biofuels Technol., 2008, Q4, pp. 7–11.

    Google Scholar 

  52. Kikhtyanin, O.V., Rubanov, A.E., Ayupov, A.B., and Echevsky, G.V., Fuel, 2010, vol. 89, pp. 3085–3092.

    Article  CAS  Google Scholar 

  53. Choi, I.H., Hwang, K.R., Han, J.S., et al., Fuel, 2015, vol. 158, pp. 98–104.

    Article  CAS  Google Scholar 

  54. Liu, S., Zhu, Q., Guan, Q., et al., Bioresource Technol., 2015, vol. 183, pp. 93–100.

    Article  CAS  Google Scholar 

  55. Wang, C., Tian, Z., and Wang, L., ChemSusChem, 2012, vol. 5, no. 10, pp. 1974–1983.

    Article  CAS  Google Scholar 

  56. Yurpalov, V.L., Drozdov, V.A., Karpova, T.R., and Lavrenov, A.V., Chem. Sustain. Develop., 2017, vol. 25, no. 1, pp. 107–113.

    Google Scholar 

  57. Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Sov. Entsiklopediya, 1988, vol. 1, p. 421.

  58. Shannon, R.D., Acta Crystallogr., Sect. A, 1976, vol. 32, pp. 751–767.

    Article  Google Scholar 

  59. Fedorova, E.D., Kazakov, M.O., Lavrenov, A.V., et al., Chem. Sustain. Develop., 2013, vol. 21, no. 1, pp. 107–113.

    Google Scholar 

  60. Karpova, T.R., Lavrenov, A.V., Buluchevsky, E.A., et al., Catal. Ind., 2014, vol. 6, no. 2, pp. 105–113.

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, ul. Neftezavodskaya 54, Omsk, 644040, Russia

    A. A. Nepomnyashchiy, E. A. Buluchevskiy, A. V. Lavrenov, V. L. Yurpalov, T. I. Gulyaeva, N. N. Leont’eva & V. P. Talzi

  2. Omsk F.M. Dostoevsky State University, ul. Neftezavodskaya 11, Omsk, 644053, Russia

    E. A. Buluchevskiy

Authors
  1. A. A. Nepomnyashchiy
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  2. E. A. Buluchevskiy
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  3. A. V. Lavrenov
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  4. V. L. Yurpalov
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  5. T. I. Gulyaeva
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Correspondence to A. A. Nepomnyashchiy.

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Original Russian Text © A.A. Nepomnyashchiy, E.A. Buluchevskiy, A.V. Lavrenov, V.L. Yurpalov, T.I. Gulyaeva, N.N. Leont’eva, V.P. Talzi, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 11, pp. 1613−1622.

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Nepomnyashchiy, A.A., Buluchevskiy, E.A., Lavrenov, A.V. et al. Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3–Al2O3 Catalysts. Russ J Appl Chem 90, 1944–1952 (2017). https://doi.org/10.1134/S1070427217120084

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  • DOI: https://doi.org/10.1134/S1070427217120084

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