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Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 1926–1930 | Cite as

In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization

  • A. B. Arbuzov
  • E. N. Kudrya
  • M. V. Trenikhin
  • V. A. Drozdov
Catalysis
  • 18 Downloads

Abstract

According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4, Al2Cl7, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced in situ in the reaction medium. Ethylene was oligomerized in n-hexane on metal chloride complexes produced in situ from Al/Fe alloys and tert-butyl chloride.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. B. Arbuzov
    • 1
    • 2
  • E. N. Kudrya
    • 1
  • M. V. Trenikhin
    • 1
    • 2
  • V. A. Drozdov
    • 1
  1. 1.Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk Scientific Center; Siberian BranchRussian Academy of SciencesOmskRussia

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