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Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene

  • Catalysis
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Abstract

Effect of the phase composition of aluminum oxide [γ- and (δ + θ) phase] and introduction of zinc additives on the catalytic properties of 0.5% Pd/Al2O3 systems in the reaction of liquid-phase hydrogenation of acetylene into ethylene under an elevated pressure in a flow-through mode was studied. An increase in the activity of the Pd catalyst upon modification with zinc is only observed in the case of a system supported by the mixed phase of (δ + θ) aluminum oxide. XAFS spectroscopy was used to find that the increase in the activity and selectivity with respect to ethylene (in the presence of carbon monoxide) on the (0.5% Pd–0.62% Zn)/(δ + θ)-Al2O3 catalyst is correlated with the formation of the PdZn intermetallic compound.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, ul. Neftezavodskaya 54, Omsk, 644040, Russia

    D. V. Glyzdova, V. L. Temerev, T. I. Gulyaeva, M. V. Trenikhin, D. A. Shlyapin & P. G. Tsyrul’nikov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117901, Russia

    N. S. Smirnova

  3. Kurchatov Institute Research Center, ul. Akademika Kurchatova 1, Moscow, 123098, Russia

    E. V. Khramov

  4. Omsk State Technical University, pr. Mira 11, Omsk, 644050, Russia

    M. V. Trenikhin

  5. Omsk Scientific Center; Siberian Branch, Russian Academy of Sciences, Omsk, 644024, Russia

    M. V. Trenikhin

Authors
  1. D. V. Glyzdova
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  2. N. S. Smirnova
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  3. V. L. Temerev
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  4. E. V. Khramov
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  5. T. I. Gulyaeva
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  6. M. V. Trenikhin
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  7. D. A. Shlyapin
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  8. P. G. Tsyrul’nikov
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Corresponding author

Correspondence to D. V. Glyzdova.

Additional information

Original Russian Text © D.V. Glyzdova, N.S. Smirnova, V.L. Temerev, E.V. Khramov, T.I. Gulyaeva, M.V. Trenikhin, D.A. Shlyapin, P.G. Tsyrul’nikov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 11, pp. 1575−1585.

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Glyzdova, D.V., Smirnova, N.S., Temerev, V.L. et al. Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene. Russ J Appl Chem 90, 1908–1917 (2017). https://doi.org/10.1134/S1070427217120035

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  • DOI: https://doi.org/10.1134/S1070427217120035

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