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Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 1893–1899 | Cite as

Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene

  • E. A. Buluchevskii
  • L. F. Saifullina
  • A. V. Lavrenov
  • T. R. Karpova
  • N. A. Glazov
Catalysis
  • 21 Downloads

Abstract

Thermodynamic calculations demonstrated that, when any C5+ alkene is subjected to ethenolysis in an excess of ethylene on a catalyst providing the occurrence of a metathesis and positional isomerization, the main reaction product is propylene. The results of the calculations were confirmed experimentally for the cases of ethenolysis of hexene-1 and heptene-1 on Re2O7/SO42-/ZrO2–Al2O3 and Re2O7/B2O3–Al2O3 catalysts.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. A. Buluchevskii
    • 1
    • 2
  • L. F. Saifullina
    • 1
  • A. V. Lavrenov
    • 1
  • T. R. Karpova
    • 1
  • N. A. Glazov
    • 2
  1. 1.Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk F.M. Dostoevsky State UniversityOmskRussia

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