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Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene

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Abstract

Thermodynamic calculations demonstrated that, when any C5+ alkene is subjected to ethenolysis in an excess of ethylene on a catalyst providing the occurrence of a metathesis and positional isomerization, the main reaction product is propylene. The results of the calculations were confirmed experimentally for the cases of ethenolysis of hexene-1 and heptene-1 on Re2O7/SO42-/ZrO2–Al2O3 and Re2O7/B2O3–Al2O3 catalysts.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, ul. Neftezavodskaya 54, Omsk, 644040, Russia

    E. A. Buluchevskii, L. F. Saifullina, A. V. Lavrenov & T. R. Karpova

  2. Omsk F.M. Dostoevsky State University, ul. Neftezavodskaya 11, Omsk, 644053, Russia

    E. A. Buluchevskii & N. A. Glazov

Authors
  1. E. A. Buluchevskii
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  2. L. F. Saifullina
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  3. A. V. Lavrenov
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  4. T. R. Karpova
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  5. N. A. Glazov
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Corresponding author

Correspondence to E. A. Buluchevskii.

Additional information

Original Russian Text © E.A. Buluchevskii, L.F. Saifullina, A.V. Lavrenov, T.R. Karpova, N.A. Glazov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 11, pp. 1560−1566.

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Buluchevskii, E.A., Saifullina, L.F., Lavrenov, A.V. et al. Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene. Russ J Appl Chem 90, 1893–1899 (2017). https://doi.org/10.1134/S1070427217120011

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  • DOI: https://doi.org/10.1134/S1070427217120011

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