Russian Journal of Applied Chemistry

, Volume 90, Issue 10, pp 1722–1726 | Cite as

Specific Features of Radical Formation in the Trialkylborane–Oxygen System and the Gluing Mechanism of Acrylate Composites

Macromolecular Compounds and Polymeric Materials
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Abstract

Fundamental study of how radicals are generated, with involvement of trialkylboranes combined with oxygen and organoelement peroxides, was carried out. It was shown that the complex process of gluing of polymeric materials with low-energy surface predominantly occurs under the action of trialkylborane unblocked from the amine complex and oxygen dissolved in the gluing formulation and also under the action of growth radicals produced in the trialkylborane–peroxide–acrylate system in the closed-system mode at room temperature. The curing process of the gluing formulation occurs in the course of time both in the bulk and on the substrate surface.

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References

  1. 1.
    Sonneshein, M.F., Webb, S.P., Kastl, P.E., et al., Macromolecules, 2004, vol. 37, pp. 7974–7978.CrossRefGoogle Scholar
  2. 2.
    Okamura, H., Sudo, A., and Endo, T., Polymer Chem., Part A, 2009, vol. 47, pp. 6163–6167.CrossRefGoogle Scholar
  3. 3.
    Zi, M., Zheng, Z., Liu, S., et al., Int. J. Adhes. Adhes., 2011, vol. 31, pp. 36–42.CrossRefGoogle Scholar
  4. 4.
    Sonnenshein, M.F., Webb, S.P., Redwine, O.D., et al., Macromolecules, 2006, vol. 39, pp. 2507–2513.CrossRefGoogle Scholar
  5. 5.
    Kablov, E.N. and Reznichenko, S.V., Kleyashchie materialy (Adhesive Materials), Moscow: KIR, 2002.Google Scholar
  6. 6.
    Trizno, M.S. and Moskalev, E.V., Klei i skleivanie (Adhesives and Gluing), Leningrad: Khimiya, 1980.Google Scholar
  7. 7.
    Kolesnikov, G.S. and Fedorova, L.S., Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1957, no. 2, pp. 236–237.Google Scholar
  8. 8.
    Furukawa, J., Tsuruta, T., Imada, T., and Furutani, H., Macromol. Chem., 1959, vol. 31, no. 2, pp. 122–139.CrossRefGoogle Scholar
  9. 9.
    Davies, A.G., Ingold, K.U., Roberts, B.R., and Tudor, R., J. Chem. Soc. B, 1971, pp. 698–712.Google Scholar
  10. 10.
    Zaremski, M.Y., Budanov, D.V., Romanov, S.A., et al., Polym. Sci. Ser. B, 2011, vol. 53, nos. 1–2, pp. 1–9.CrossRefGoogle Scholar
  11. 11.
    Zaremski, M.Yu., Garina, E.S., Gurskii, M.E., and Bubnov, Yu.N., Polym. Sci. Ser. B, 2013, vol. 55, nos. 5–6, pp. 304–326.CrossRefGoogle Scholar
  12. 12.
    Zhang Z.C., Chung T.C.M., Macromolecules, 2006, vol. 39, pp. 5184–5189.Google Scholar
  13. 13.
    Razuvaev, G.A., Dodonov, V.A., Tsvetkov, V.G., et al., Vysokomol. Soedin., 1988, vol. 30, no. 2, pp. 146–150.Google Scholar
  14. 14.
    Dodonov, V.A., Morozov, O.S., Grishin, D.F., et al., Dokl. Akad. Nauk SSSR, 1980, vol. 255, no. 5, pp. 1123–1127.Google Scholar
  15. 15.
    Dodonov, V.A., Lomakin, S.S., and Gulenova, M.V., Klei, Germetiki, Tekhnol., 2013, no. 11, pp. 29–33.Google Scholar
  16. 16.
    Dodonov, V.A., Starostina, T.I., Kuropatov, V.A., et al., Russ. J. Appl. Chem., 2017, vol. 90, no. 1, pp. 77–83.CrossRefGoogle Scholar
  17. 17.
    Dodonov, V.A., Grishin, D.F., and Aksenova, I.N., Vysokomol. Soedin., Ser. B, 1993, vol. 35, no. 12, pp. 2070–2072.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  1. 1.Lobachevsky National Research State University of Nizhny NovgorodNizhny NovgorodRussia

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