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Russian Journal of Applied Chemistry

, Volume 90, Issue 10, pp 1666–1673 | Cite as

Solid-State Hydrogen-Generating Composites Based on Sodium Borohydride: Effect of the Heat Treatment of Boron–Cobalt Catalysts on the Hydrogen Generation Rate

  • O. V. Netskina
  • O. V. Komova
  • I. P. Prosvirin
  • A. A. Pochtar’
  • A. M. Ozerova
  • V. I. Simagina
Various Technological Processes

Abstract

Calcined boron–cobalt catalysts prepared by reduction of cobalt chloride in an aqueous sodium borohydride solution can be successfully used as components of pelletized solid-state hydrogen-generating composites based on sodium borohydride. Morphological changes and phase and chemical transformations occurring in the catalysts with an increase in the calcination temperature were studied. The catalyst performance in hydrolysis of sodium borohydride was determined. The hydrogen generation rate depends on the specific surface area of the calcined sample.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • O. V. Netskina
    • 1
    • 2
  • O. V. Komova
    • 1
  • I. P. Prosvirin
    • 1
    • 2
  • A. A. Pochtar’
    • 1
  • A. M. Ozerova
    • 1
  • V. I. Simagina
    • 1
    • 3
  1. 1.Boreskov Institute of CatalysisSiberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk National Research State UniversityNovosibirskRussia
  3. 3.Siberian Institute of ManagementBranch of the Russian Presidential Academy of National Economy and Public AdministrationNovosibirskRussia

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