Russian Journal of Applied Chemistry

, Volume 90, Issue 10, pp 1579–1585 | Cite as

Synthesis of Highly Dispersed Zirconium Diboride for Fabrication of Special-Purpose Ceramic

  • Yu. L. Krutskii
  • E. A. Maksimovskii
  • M. V. Popov
  • O. V. Netskina
  • T. M. Krutskaya
  • N. Yu. Cherkasova
  • T. S. Kvashina
  • E. A. Drobyaz
Inorganic Synthesis and Industrial Inorganic Chemistry

Abstract

Reduction of zirconium dioxide with boron carbide and nanofibrous carbon in argon yielded a highly dispersed powder of zirconium diboride. Characteristics of zirconium diboride powders were examined by various analytical methods. The material obtained is represented by a single phase, zirconium diboride. Powder particles are for the most part aggregated. The average size of particles and aggregates is 10.9–12.9 μm with a wide size distribution. The specific surface area of the samples is 1.8–3.6 m2 g–1. The oxidation of zirconium diboride begins at a temperature of 640°C The optimal synthesis parameters were determined: ZrO2: B4C: C molar ratio of 2: 1: 3 (in accordance with stoichiometry), process temperature 1600–1700°C, synthesis duration 20 min.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Yu. L. Krutskii
    • 1
  • E. A. Maksimovskii
    • 2
    • 3
  • M. V. Popov
    • 1
  • O. V. Netskina
    • 3
    • 5
  • T. M. Krutskaya
    • 4
  • N. Yu. Cherkasova
    • 1
  • T. S. Kvashina
    • 1
  • E. A. Drobyaz
    • 1
  1. 1.Novosibirsk State Technical UniversityNovosibirskRussia
  2. 2.Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  3. 3.Novosibirsk State UniversityNovosibirskRussia
  4. 4.Novosibirsk State Architectural-Constructional UniversityNovosibirskRussia
  5. 5.Boreskov Institute of Catalysis, Siberian BranchRussian Academy of SciencesNovosibirskRussia

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