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Synthesis of Highly Dispersed Zirconium Diboride for Fabrication of Special-Purpose Ceramic

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Reduction of zirconium dioxide with boron carbide and nanofibrous carbon in argon yielded a highly dispersed powder of zirconium diboride. Characteristics of zirconium diboride powders were examined by various analytical methods. The material obtained is represented by a single phase, zirconium diboride. Powder particles are for the most part aggregated. The average size of particles and aggregates is 10.9–12.9 μm with a wide size distribution. The specific surface area of the samples is 1.8–3.6 m2 g–1. The oxidation of zirconium diboride begins at a temperature of 640°C The optimal synthesis parameters were determined: ZrO2: B4C: C molar ratio of 2: 1: 3 (in accordance with stoichiometry), process temperature 1600–1700°C, synthesis duration 20 min.

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Authors and Affiliations

  1. Novosibirsk State Technical University, ul. Karla Marksa 20, Novosibirsk, 630073, Russia

    Yu. L. Krutskii, M. V. Popov, N. Yu. Cherkasova, T. S. Kvashina & E. A. Drobyaz

  2. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. A. Maksimovskii

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    E. A. Maksimovskii & O. V. Netskina

  4. Novosibirsk State Architectural-Constructional University, ul. Leningradskaya 113, Novosibirsk, 630008, Russia

    T. M. Krutskaya

  5. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    O. V. Netskina

Authors
  1. Yu. L. Krutskii
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  2. E. A. Maksimovskii
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  3. M. V. Popov
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  4. O. V. Netskina
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  5. T. M. Krutskaya
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  6. N. Yu. Cherkasova
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  7. T. S. Kvashina
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  8. E. A. Drobyaz
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Corresponding author

Correspondence to Yu. L. Krutskii.

Additional information

Original Russian Text © Yu.L. Krutskii, E.A. Maksimovskii, M.V. Popov, O.V. Netskina, T.M. Krutskaya, N.Yu. Cherkasova, T.S. Kvashina, E.A. Drobyaz, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 10, pp. 1295−1302.

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Krutskii, Y.L., Maksimovskii, E.A., Popov, M.V. et al. Synthesis of Highly Dispersed Zirconium Diboride for Fabrication of Special-Purpose Ceramic. Russ J Appl Chem 90, 1579–1585 (2017). https://doi.org/10.1134/S1070427217100044

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  • DOI: https://doi.org/10.1134/S1070427217100044

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