Russian Journal of Applied Chemistry

, Volume 88, Issue 9, pp 1464–1471 | Cite as

Preparation of cerium oxalate from spent iron–potassium catalyst for dehydrogenation of isoamylenes into isoprene

  • A. Sh. Bikmurzin
  • A. A. Lamberov
  • R. G. Romanova
Catalysis
  • 58 Downloads

Abstract

The cerium recovery in the oxalate form from spent iron–potassium catalyst for dehydrogenation of isoamylenes into isoprene was studied. The optimum conditions allowing preparation of the pure product with high degree of recovery were found. It was proved by X-ray diffraction, thermal gravimetric analysis, differential scanning calorimetry, and X-ray fluorescence analysis that the product obtained by the precipitation was cerium oxalate decahydrate containing no less than 98 wt % main substance.

Keywords

Oxalate Cerium Dehydrogenation Isoprene Isoamylenes 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. Sh. Bikmurzin
    • 1
  • A. A. Lamberov
    • 2
  • R. G. Romanova
    • 3
  1. 1.Nizhnekamskneftekhim PAONizhnekamsk, TatarstanRussia
  2. 2.Kazan (Volga Region) Federal UniversityKazan, TatarstanRussia
  3. 3.Kazan National Research Technological UniversityKazan, TatarstanRussia

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