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Chromium(III) cross-linked poly(acylamide co-2-acrylamido-2-methyl-1-propanesulfonic acid) hydrogels, prepared by frontal polymerization in aqueous solutions

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Abstract

Polyelectrolyte hydrogels based on copolymers of acrylamide with 2-acrylamido-2-methylpropanesulfonic acid were prepared by frontal copolymerization in dilute aqueous solutions of the monomers using ammonium persulfate as initiator chromium triacetate as cross-linking agent. The influence of the monomer molar ratio, initiator and cross-linker concentration on the possibility of performing the copolymerization and monomer reactivity ratios in the frontal mode, and on the characteristics of the obtained hydrogels was examined.

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References

  1. Ganji, F., and Vasheghani-Farahani, E., Iran. Polym. J., 2009, vol. 18, no. 1, pp. 63–88.

    CAS  Google Scholar 

  2. Rudzinski, W.E., Dave, A.M., Vaishnav, U.H., et al., Des. Monomers. Polym., 2002, vol. 5, no. 1, pp. 39–65.

    Article  CAS  Google Scholar 

  3. Zohuriaan-Mehr, MJ., and Kabiri, K., Iran. Polym. J., 2008, vol. 17, no. 6, pp. 451–477.

    CAS  Google Scholar 

  4. Omidian, H. and Park, K., in Biomedical Applications of Hydrogels Handbook, New York: Springer, 2010, pp. 1,2.

    Book  Google Scholar 

  5. Khokhlov, A. R. and Osada, Y., Polymer Gels and Networks, New York: Marcel Dekker, 2002.

    Google Scholar 

  6. Kwon, H.J. and Gong, J.P., Curr. Opin. Colloid. Interface. Sci., 2006, vol. 11, no. 6, pp. 345–350.

    Article  CAS  Google Scholar 

  7. Mark, H.F., Encyclopedia of Polymer Science and Technology, John Wiley and Sons, 2005, 3rd ed., vol. 1, ch.1.

  8. Fisher, L.W., Sochor, A.R., and Tan, J. S., Macromolecules, 1977, vol. 10, no. 5, pp. 949–954.

    Article  CAS  Google Scholar 

  9. Plochocka, K., J. Macromol. Sci. Rev. Macromol. Chem., 1981, vol. 20, no. 1, pp. 67–148.

    Article  Google Scholar 

  10. Candau, F., Zekhnini, Z., and Heatley, F., Macromolecules, 1986, vol. 19, no. 7, pp. 1895–1902.

    Article  CAS  Google Scholar 

  11. Borckmans, P., De Kepper, P., Khokhlov, A.R., and Metens, S., Chemomechanical Instabilities in Responsive Material., Dordrecht: Springer, 2009.

    Book  Google Scholar 

  12. Davtyan, S.P., Berlin, A.A., and Tonoyan, A.O., Rev. J. Chem., 2011, vol. 1, no. 1, pp. 56–92.

    Article  Google Scholar 

  13. Pojman, J.A., in Polymer Science: a Comprehensive Reference, Elsevier, 2012, vol. 4, pp. 957–980.

    Google Scholar 

  14. Chechilo, N.M., Khvilivitskii, R.Yu., and Enikolopyan, N.S., Dokl. Akad. Nauk SSSR, 1972, vol. 204, no. 5, pp. 1180–1181.

    CAS  Google Scholar 

  15. Pojman, J.A., J. Am. Chem. Soc., 1991, vol. 113, no. 16, pp. 6284–6286.

    Article  CAS  Google Scholar 

  16. Pojman, J.A., Ilyashenko, V.M., and Khan, A.M., J. Chem. Soc. Faraday Trans., 1996, vol. 92, no. 16, pp. 2825–2837.

    Article  CAS  Google Scholar 

  17. Khan, A.M. and Pojman, J.A., Trends Polym. Sci., U.K.: Cambridge, 1996.

    Google Scholar 

  18. Washington, R.P. and Steinbock, O.J., Am. Chem. Soc., 2001, vol. 123, no. 32, pp. 7933–7934.

    Article  CAS  Google Scholar 

  19. Lu, G.D., Yan, Q.Z., and Ge, C.C., Polym. Int., 2007, vol. 56, no. 8, pp. 1016–1020.

    Article  CAS  Google Scholar 

  20. Feng, Q., Yan, Q.Z., and Ge, C.C., Chin. J. Polym. Sci., 2009, vol. 27, no. 5, pp. 747–753.

    Article  CAS  Google Scholar 

  21. Gavini, E., Mariani, A., Rassu, G., et al., Eur. Polym. J., 2009, vol. 45, no. 3, pp. 690–699.

    Article  CAS  Google Scholar 

  22. Alzari, V., Monticelli, O., Nuvoli, D., et al., Biomacromolecules, 2009, vol. 10, no. 9, pp. 2672–2677.

    Article  CAS  Google Scholar 

  23. Caria, G., Alzari, V., Monticelli, O., et al., J. Polym. Sci. Part A: Polym. Chem., 2009, vol. 47, no. 5, pp. 1422–1428.

    Article  CAS  Google Scholar 

  24. Scognamillo, S., Alzari, V., Nuvoli, D., and Mariani, A., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 11, pp. 2486–2490.

    Article  CAS  Google Scholar 

  25. Alzari, V., Mariani, A., Monticelli, O., et al., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 23, pp. 5375–5381.

    Article  CAS  Google Scholar 

  26. Alzari, V., Nuvoli, D., Scognamillo, S., et al., J. Mater. Chem., 2011, vol. 21, no. 24, pp. 8727–8733.

    Article  CAS  Google Scholar 

  27. Scognamillo, S., Alzari, V., Nuvoli, D., et al., J. Polym. Sci. Part A: Polym. Chem., 2011, vol. 49, no. 5, pp. 1228–1234.

    Article  CAS  Google Scholar 

  28. Illescas, J., Sanna, R., Alzari, V., et al., J. Polym. Sci. Part A: Polym. Chem., 2013, vol. 51, no. 21, pp. 4618–4625.

    CAS  Google Scholar 

  29. Li, J., Ji, J., Xia, J., and Li, B., Carbohydrate Polymers, 2012, vol. 87, no. 1, pp. 757–763.

    Article  CAS  Google Scholar 

  30. Grinyuk, E.V., Duk, O.G., Sheresh, I.V., and Krul’, L.P., Russ. J. Applied Chem., 2014, vol. 87, no. 12, pp. 1913–1917.

    Article  CAS  Google Scholar 

  31. Airapetyan, S.M., Manukyan, L.S., Babanova, A.S., et al., Izv. Nats. Akad. Nauk Resp. Arm. Gos. Inzh. Univ. Arm., Ser. Tekh. Nauk, 2003, vol. 56, no. 1, pp. 52–60.

    CAS  Google Scholar 

  32. Tonoyan, A.P., Ketyan, A.G., Zakaryan, A.O., et al., Khim. Zh. Arm., 2010, vol. 63, no. 2, pp. 193–204.

    CAS  Google Scholar 

  33. Tu, J., Chen, L., Fang, Y., et al., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 4, pp. 823–831.

    Article  CAS  Google Scholar 

  34. Coates, J., in Encyclopedia of Analytical Chemistry, Chichester: John Wiley & Sons Ltd., 2000, pp. 10815–10837.

    Google Scholar 

  35. Odian, G., Principles of Polymerization, New Jersey: John Wiley and Sons, 2004., 4th ed.

    Book  Google Scholar 

  36. Travas-Sejdic, J. and Easteal A., J. Appl. Polym. Sci., 2000. vol. 75. no. 5, pp. 619–628.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Belarussian State University, Leningradskaya str. 14, Minsk, 220030, Belarus

    M. Ghazinezhad, E. V. Grinyuk & L. P. Krul’

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  1. M. Ghazinezhad
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  2. E. V. Grinyuk
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  3. L. P. Krul’
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Correspondence to M. Ghazinezhad.

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Ghazinezhad, M., Grinyuk, E.V. & Krul’, L.P. Chromium(III) cross-linked poly(acylamide co-2-acrylamido-2-methyl-1-propanesulfonic acid) hydrogels, prepared by frontal polymerization in aqueous solutions. Russ J Appl Chem 88, 1368–1374 (2015). https://doi.org/10.1134/S1070427215080224

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  • DOI: https://doi.org/10.1134/S1070427215080224

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