Russian Journal of Applied Chemistry

, Volume 88, Issue 8, pp 1368–1374 | Cite as

Chromium(III) cross-linked poly(acylamide co-2-acrylamido-2-methyl-1-propanesulfonic acid) hydrogels, prepared by frontal polymerization in aqueous solutions

Various Technological Processes
  • 38 Downloads

Abstract

Polyelectrolyte hydrogels based on copolymers of acrylamide with 2-acrylamido-2-methylpropanesulfonic acid were prepared by frontal copolymerization in dilute aqueous solutions of the monomers using ammonium persulfate as initiator chromium triacetate as cross-linking agent. The influence of the monomer molar ratio, initiator and cross-linker concentration on the possibility of performing the copolymerization and monomer reactivity ratios in the frontal mode, and on the characteristics of the obtained hydrogels was examined.

Keywords

Front Velocity Initiator Concentration Water Absorbency Front Temperature Frontal Polymerization 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Ganji, F., and Vasheghani-Farahani, E., Iran. Polym. J., 2009, vol. 18, no. 1, pp. 63–88.Google Scholar
  2. 2.
    Rudzinski, W.E., Dave, A.M., Vaishnav, U.H., et al., Des. Monomers. Polym., 2002, vol. 5, no. 1, pp. 39–65.CrossRefGoogle Scholar
  3. 3.
    Zohuriaan-Mehr, MJ., and Kabiri, K., Iran. Polym. J., 2008, vol. 17, no. 6, pp. 451–477.Google Scholar
  4. 4.
    Omidian, H. and Park, K., in Biomedical Applications of Hydrogels Handbook, New York: Springer, 2010, pp. 1,2.CrossRefGoogle Scholar
  5. 5.
    Khokhlov, A. R. and Osada, Y., Polymer Gels and Networks, New York: Marcel Dekker, 2002.Google Scholar
  6. 6.
    Kwon, H.J. and Gong, J.P., Curr. Opin. Colloid. Interface. Sci., 2006, vol. 11, no. 6, pp. 345–350.CrossRefGoogle Scholar
  7. 7.
    Mark, H.F., Encyclopedia of Polymer Science and Technology, John Wiley and Sons, 2005, 3rd ed., vol. 1, ch.1.Google Scholar
  8. 8.
    Fisher, L.W., Sochor, A.R., and Tan, J. S., Macromolecules, 1977, vol. 10, no. 5, pp. 949–954.CrossRefGoogle Scholar
  9. 9.
    Plochocka, K., J. Macromol. Sci. Rev. Macromol. Chem., 1981, vol. 20, no. 1, pp. 67–148.CrossRefGoogle Scholar
  10. 10.
    Candau, F., Zekhnini, Z., and Heatley, F., Macromolecules, 1986, vol. 19, no. 7, pp. 1895–1902.CrossRefGoogle Scholar
  11. 11.
    Borckmans, P., De Kepper, P., Khokhlov, A.R., and Metens, S., Chemomechanical Instabilities in Responsive Material., Dordrecht: Springer, 2009.CrossRefGoogle Scholar
  12. 12.
    Davtyan, S.P., Berlin, A.A., and Tonoyan, A.O., Rev. J. Chem., 2011, vol. 1, no. 1, pp. 56–92.CrossRefGoogle Scholar
  13. 13.
    Pojman, J.A., in Polymer Science: a Comprehensive Reference, Elsevier, 2012, vol. 4, pp. 957–980.Google Scholar
  14. 14.
    Chechilo, N.M., Khvilivitskii, R.Yu., and Enikolopyan, N.S., Dokl. Akad. Nauk SSSR, 1972, vol. 204, no. 5, pp. 1180–1181.Google Scholar
  15. 15.
    Pojman, J.A., J. Am. Chem. Soc., 1991, vol. 113, no. 16, pp. 6284–6286.CrossRefGoogle Scholar
  16. 16.
    Pojman, J.A., Ilyashenko, V.M., and Khan, A.M., J. Chem. Soc. Faraday Trans., 1996, vol. 92, no. 16, pp. 2825–2837.CrossRefGoogle Scholar
  17. 17.
    Khan, A.M. and Pojman, J.A., Trends Polym. Sci., U.K.: Cambridge, 1996.Google Scholar
  18. 18.
    Washington, R.P. and Steinbock, O.J., Am. Chem. Soc., 2001, vol. 123, no. 32, pp. 7933–7934.CrossRefGoogle Scholar
  19. 19.
    Lu, G.D., Yan, Q.Z., and Ge, C.C., Polym. Int., 2007, vol. 56, no. 8, pp. 1016–1020.CrossRefGoogle Scholar
  20. 20.
    Feng, Q., Yan, Q.Z., and Ge, C.C., Chin. J. Polym. Sci., 2009, vol. 27, no. 5, pp. 747–753.CrossRefGoogle Scholar
  21. 21.
    Gavini, E., Mariani, A., Rassu, G., et al., Eur. Polym. J., 2009, vol. 45, no. 3, pp. 690–699.CrossRefGoogle Scholar
  22. 22.
    Alzari, V., Monticelli, O., Nuvoli, D., et al., Biomacromolecules, 2009, vol. 10, no. 9, pp. 2672–2677.CrossRefGoogle Scholar
  23. 23.
    Caria, G., Alzari, V., Monticelli, O., et al., J. Polym. Sci. Part A: Polym. Chem., 2009, vol. 47, no. 5, pp. 1422–1428.CrossRefGoogle Scholar
  24. 24.
    Scognamillo, S., Alzari, V., Nuvoli, D., and Mariani, A., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 11, pp. 2486–2490.CrossRefGoogle Scholar
  25. 25.
    Alzari, V., Mariani, A., Monticelli, O., et al., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 23, pp. 5375–5381.CrossRefGoogle Scholar
  26. 26.
    Alzari, V., Nuvoli, D., Scognamillo, S., et al., J. Mater. Chem., 2011, vol. 21, no. 24, pp. 8727–8733.CrossRefGoogle Scholar
  27. 27.
    Scognamillo, S., Alzari, V., Nuvoli, D., et al., J. Polym. Sci. Part A: Polym. Chem., 2011, vol. 49, no. 5, pp. 1228–1234.CrossRefGoogle Scholar
  28. 28.
    Illescas, J., Sanna, R., Alzari, V., et al., J. Polym. Sci. Part A: Polym. Chem., 2013, vol. 51, no. 21, pp. 4618–4625.Google Scholar
  29. 29.
    Li, J., Ji, J., Xia, J., and Li, B., Carbohydrate Polymers, 2012, vol. 87, no. 1, pp. 757–763.CrossRefGoogle Scholar
  30. 30.
    Grinyuk, E.V., Duk, O.G., Sheresh, I.V., and Krul’, L.P., Russ. J. Applied Chem., 2014, vol. 87, no. 12, pp. 1913–1917.CrossRefGoogle Scholar
  31. 31.
    Airapetyan, S.M., Manukyan, L.S., Babanova, A.S., et al., Izv. Nats. Akad. Nauk Resp. Arm. Gos. Inzh. Univ. Arm., Ser. Tekh. Nauk, 2003, vol. 56, no. 1, pp. 52–60.Google Scholar
  32. 32.
    Tonoyan, A.P., Ketyan, A.G., Zakaryan, A.O., et al., Khim. Zh. Arm., 2010, vol. 63, no. 2, pp. 193–204.Google Scholar
  33. 33.
    Tu, J., Chen, L., Fang, Y., et al., J. Polym. Sci. Part A: Polym. Chem., 2010, vol. 48, no. 4, pp. 823–831.CrossRefGoogle Scholar
  34. 34.
    Coates, J., in Encyclopedia of Analytical Chemistry, Chichester: John Wiley & Sons Ltd., 2000, pp. 10815–10837.Google Scholar
  35. 35.
    Odian, G., Principles of Polymerization, New Jersey: John Wiley and Sons, 2004., 4th ed.CrossRefGoogle Scholar
  36. 36.
    Travas-Sejdic, J. and Easteal A., J. Appl. Polym. Sci., 2000. vol. 75. no. 5, pp. 619–628.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • M. Ghazinezhad
    • 1
  • E. V. Grinyuk
    • 1
  • L. P. Krul’
    • 1
  1. 1.Belarussian State UniversityMinskBelarus

Personalised recommendations