Features of the Reaction of Dimedone with Some Amines in the Presence of Mercury(II) Acetate

Abstract

Regiochemistry of the reaction of N-substituted propargylamines with dimedone in the presence of mercury(II) acetate was studied. Xanthene and diene derivatives, as well as symmetric mercury aminopropinides, were obtained, for one of which the crystallographic parameters are given.

This is a preview of subscription content, access via your institution.

Scheme
Fig. 1.
Scheme

REFERENCES

  1. 1

    Badanyan, Sh.O., Chobanyan, Zh.A., Tirakyan, M.R., and Danielyan, A.O., Chem. Heterocycl. Compd., 1998, vol. 34, no. 7, p. 781. https://doi.org/10.1007/BF02251682

    CAS  Article  Google Scholar 

  2. 2

    El Ashry, E.S.H., Awad, L.F., El Kilany, Y., and Ibrahim, E.I., Adv. Heterocycl. Chem., 2009, vol. 98, p. 1. https://doi.org/10.1016/S0065-2725(09)09801-8

    CAS  Article  Google Scholar 

  3. 3

    Knight, D.W. and Little, P.B., J. Chem. Soc. Perkin Trans. 1, 2001, no. 14, p. 1771. https://doi.org/10.1039/B103834F

    Article  Google Scholar 

  4. 4

    Vazquez, R., de la Fuente, M.C., Castedo, L., and Dominguez, D., Synlett, 1994, no. 6, p. 433. https://doi.org/10.1055/s-1994-22878

    CAS  Article  Google Scholar 

  5. 5

    Ishibashi, H., Takagaki, K., Imada, N., and Ikeda, M., Synlett, 1994, no. 1, p. 49. https://doi.org/10.1055/s-1994-22734

    Article  Google Scholar 

  6. 6

    Jha, A. and Beal, J., Tetrahedron Lett, 2004, vol. 45, p. 8999. https://doi.org/10.1016/j.tetlet.2004.10.046

    CAS  Article  Google Scholar 

  7. 7

    Singh, K., Singh, J., and Singh, H., Tetrahedron, 1996, vol. 52, p. 14273. https://doi.org/10.1016/0040-4020(96)00879-4

    CAS  Article  Google Scholar 

  8. 8

    Khalafi-Nezhad, A., Panahi, F., Mohammadi, S., and Foroughi, H.O., J. Iran. Chem. Soc., 2012, vol. 10, p. 189. https://doi.org/10.1007/s13738-012-0140-1

    CAS  Article  Google Scholar 

  9. 9

    Castillo, A.M., Patiny, L., and Wist, J., J. Magn. Reson., 2011, vol. 209, p. 123. https://doi.org/10.1016/j.jmr.2010.12.008

    CAS  Article  PubMed  Google Scholar 

  10. 10

    Sheldrick, G.M., Acta Crysttallogr. (A), 2007, vol. 64, p. 112. https://doi.org/10.1107/S0108767307043930

    CAS  Article  Google Scholar 

  11. 11

    North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr. (A), 1968, vol. 24, p. 351. https://doi.org/10.1107/S0567739468000707

    Article  Google Scholar 

Download references

Author information

Affiliations

Authors

Corresponding author

Correspondence to N. G. Hobosyan.

Ethics declarations

The authors declare no conflicts of interest.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Hobosyan, N.G., Balyan, K.V., Nersisyan, H.S. et al. Features of the Reaction of Dimedone with Some Amines in the Presence of Mercury(II) Acetate. Russ J Gen Chem 90, 2518–2521 (2020). https://doi.org/10.1134/S1070363220120312

Download citation

Keywords:

  • dimedone
  • xanthenedione
  • mercury aminoacetylenide
  • mercury(II) acetate