Interaction of Polyacrylic Acid with Copper, Cobalt, and Nickel Ions in Aqueous Solutions

Abstract

Potentiometric and spectrophotometric titration methods were applied to study the relationships in the interaction of polyacrylic acid with copper, cobalt, and nickel ions in aqueous solutions. It was shown that, in aqueous solutions at pH ~ 3, polyacrylic acid does not form complexes with cobalt and nickel ions. A complex is formed with copper ions, but the equilibrium of the complexing reaction is strongly biased towards copper aqua complexes. The sizes of the metal particles were determined using transmission electron microscopy. The metal particles synthesized in the presence of polyacrylic acid exhibited a fairly broad size distribution.

This is a preview of subscription content, log in to check access.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

REFERENCES

  1. 1

    Qi, T., Wang, X., Yang, J., and Xiao, F., J. Mat. Sci., 2019, vol. 30, p. 12669. https://doi.org/10.1007/s10854-019-01630-4

    CAS  Article  Google Scholar 

  2. 2

    Abdurakhmanov, U., Boitmuratov, F.T., Mukhamedov, G.I., Fionov, A.S., and Yurkov, G.Yu., J. Com. Tech. Electr., 2010, vol. 55, p. 221. https://doi.org/10.1134/S1064226910020154

    Article  Google Scholar 

  3. 3

    Suwanwatan, W., Yarlagadda, S., and Gillespie, J.W.Jr., J. Mat. Sci., 2003, vol. 38, p. 565. https://doi.org/10.1023/A:1021854026668

    Article  Google Scholar 

  4. 4

    Chernavskii, P.A., Pankina, G.V., Lermontov, A.S., and Lunin, V.V.,Kinet. Catal., 2003, vol. 44, p. 657. https://doi.org/10.1023/A:1026146123264

    CAS  Article  Google Scholar 

  5. 5

    Papisov, I.M., Polymer Sci., B, 1997, vol. 39, p. 122.

    Google Scholar 

  6. 6

    Krotikova, O.A., Ozerin, A.S., Radchenko, F.S., and Novakov, I.A.,Polym. Sci., A, 2017, vol. 59, p. 288. https://doi.org/10.1134/S0965545X17030105

    CAS  Article  Google Scholar 

  7. 7

    Ustyakina, D.R., Chevtaev, A.S., Tabunschikov, A.I., Ozerin, A.S., Radchenko, Ph.S., and Novakov, I.A., Polymer Sci., B, 2019, vol. 61, p. 261. https://doi.org/10.1134/S1560090419030151

    CAS  Article  Google Scholar 

  8. 8

    Novakov, I.A., Radchenko, F.S., Ozerin, A.S., Chevtaev, A.S., Tabunshchikov, A.I., and Ustyakina, D.R., Izv. Volgogr. Gos. Tekh. Univ., Ser. Khim. Tekhnol. Elementoorg. Monom. Polim. Mater., 2019, no. 5(228), p. 74.

    Google Scholar 

  9. 9

    Sergeev, B.M., Kiryukhin, M.V., Bakhov, F.N., and Sergeev, V.G.,Vestn. Mosk. Univ., Ser. 2: Khim., 2001, vol. 42, no. 5, p. 308.

    CAS  Google Scholar 

  10. 10

    Zezin, A.A., Feldman, V.I., Abramchuk, S.S., Danelyan, G.V., Dyo, V.V., Plamper, F.A., Mullerd, A.H.E., and Pergushov, D.V., Phys. Chem. Chem. Phys., 2015, vol. 17, p. 11490. https://doi.org/10.1039/C5CP00269A

    CAS  Article  PubMed  Google Scholar 

  11. 11

    Schneider, C.A., Rasband, W.S., and Eliceiri, K.W., Nat. Methods, 2012, vol. 9, p. 671. https://doi.org/10.1038/nmeth.2089

    CAS  Article  PubMed  PubMed Central  Google Scholar 

Download references

Funding

This study was financially supported by the Russian Foundation for Basic Research (project no. 18-03-00594).

Author information

Affiliations

Authors

Corresponding author

Correspondence to A. S. Ozerin.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Chevtaev, A.S., Tabunshchikov, A.I., Ozerin, A.S. et al. Interaction of Polyacrylic Acid with Copper, Cobalt, and Nickel Ions in Aqueous Solutions. Russ J Gen Chem 90, 870–873 (2020). https://doi.org/10.1134/S1070363220050187

Download citation

Keywords:

  • polymer–metal complexes
  • copper
  • nickel
  • and cobalt ions
  • polyacrylic acid
  • nanoparticles