Synthesis and Acid–Base, Absorption, and Fluorescence Properties of Phthalocyanine Derivatives

Abstract

Tetrakis{5,6-bis(4-tert-butylphenyl)pyrazino[2,3-c]}porphyrazine and tetra(4-tert-butyl)phthalocyanine have been synthesized, and their acid–base properties and electronic absorption and fluorescence spectra in acetonitrile and toluene at 298 and 295 K, respectively, have been studied. The synthesized compounds have been identified by electronic absorption and1H NMR spectroscopy and mass spectrometry. The effect of substituents in the molecular fragments of the macrocycle on the electronic and optical properties of the synthesized compounds has been estimated.

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Funding

This study was performed under financial support by the Russian Science Foundation (project no. 19-73-20079) using the facilities of the Upper Volga Regional Center for Physicochemical Studies.

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Correspondence to Yu. B. Ivanova.

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Ivanova, Y.B., Dmitrieva, O.A., Khrushkova, Y.V. et al. Synthesis and Acid–Base, Absorption, and Fluorescence Properties of Phthalocyanine Derivatives. Russ J Gen Chem 90, 852–857 (2020). https://doi.org/10.1134/S1070363220050151

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Keywords:

  • phthalocyanine
  • porphyrazine
  • acid–base properties
  • fluorescence