New Formula Type of Phosphates with Langbeinite Mineral Structure

Abstract

Phosphates of the new formula type A5/3MgE4/3(PO4)3 (A = K, Rb; E = Ti, Zr) with a langbeinite structure have been synthesized via the sol-gel method followed by heat treatment and studied using X-ray diffraction, IR spectroscopy, and electron microscopy methods.

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Funding

This study was financially supported by the Russian Foundation for Basic Research (project no. 18-29-12063).

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Correspondence to V. I. Pet’kov.

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Pet’kov, V.I., Alekseev, A.A., Asabina, E.A. et al. New Formula Type of Phosphates with Langbeinite Mineral Structure. Russ J Gen Chem 90, 680–685 (2020). https://doi.org/10.1134/S1070363220040192

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Keywords:

  • phosphates
  • langbeinite structure
  • Rietveld method
  • thermal expansion