Abstract
Phosphates of the new formula type A5/3MgE4/3(PO4)3 (A = K, Rb; E = Ti, Zr) with a langbeinite structure have been synthesized via the sol-gel method followed by heat treatment and studied using X-ray diffraction, IR spectroscopy, and electron microscopy methods.
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REFERENCES
Sarrign, M.L.M., Clemente, A.R., and Vila, L.M., J. Solid State Chem., 1990, vol. 84, p. 308. https://doi.org/10.1016/0022-4596(90)90329-V
Zatovskii, I.V., Slobodyanik, N.S., Ushchapivskaya, T.I., Ogorodnik, I.V., and Babarik, A.A., Russ. J. Appl. Chem., 2006, vol. 79, p. 10. https://doi.org/10.1134/S1070427206010034
Pet’kov, V.I., Shchelokov, I.A., Surazhskaya, M.D., Palkina, K.K., Kanishcheva, A.S., and Knyazev, A.V., Russ. J. Inorg. Chem., 2010, vol. 55, p. 1352. https://doi.org/10.1134/S0036023610090044
Souamti, A., Martín, I.R., Zayani, L., Hernández-Rodríguez, M.A., Soler-Carracedo, K., Lozano-Gorrín, A.D., Lalla, E., and Ben Hassen Chehimi, D., J. Luminescence, 2016, vol. 177, p. 160. https://doi.org/10.1016/j.jlumin.2016.04.045
Battle, P.D., Gibb, T.C., Nixon, S., and Harrison, W.T.A., J. Solid State Chem., 1988, vol. 75, p. 21. https://doi.org/10.1016/0022-4596(88)90299-X
Ogorodnyk, I.V., Zatovsky, I.V., Slobodyanik, N.S., Baumer, V.N., and Shishkin, O.V., J. Solid State Chem., 2006, vol. 179, p. 3461. https://doi.org/10.1016/j.jssc.2006.07.015
Sadhasivam, S., Manivel, P., Jeganathan, K., Jayasankar, C.K., and Rajesh, N.P., Mater. Lett., 2017, vol. 188, p. 399. https://doi.org/10.1016/j.matlet.2016.11.091
Liu, J., Duan, X., Zhang, Y., Li, Z., Yu, F., and Jiang, H., J. Alloys Compd., 2016, vol. 660, p. 356. https://doi.org/10.1016/j.jallcom.2015.11.147
Pet’kov, V.I., Asabina, E.A., Markin, A.V., Alekseev, A.A., and Smirnova, N.N., J. Therm. Anal. Cal., 2016, vol. 124, no. 3, p. 1535. https://doi.org/10.1007/s10973-016-5319-8
Souamti, A., Kahlaoui M, Mohammed, B., LozanoGorrín, A.D., and Chehimi, D.B.H., Ceram. Int., 2017, vol. 43, no. 14, p. 10939. https://doi.org/10.1016/j.ceramint.2017.05.132
Asabina, E.A., Pet’kov, V.I., Gobechiya, E.R., Kabalov, Yu.K., Pokholok, K.V., and Kurazhkovskaya, V.S., Russ. J. Inorg. Chem., 2008, vol. 53, p. 40. https://doi.org/10.1134/S0036023608010075
Tsyrenova, G.D. and Pavlova, N.N., Inorg. Mater., 2011, vol. 47, no. 7, p. 786. https://doi.org/10.1134/S0020168511070235
Pet’kov, V.I., Asabina, E.A., Lukuttsov, A.A., Korchemkin, I.V., Alekseev, A.A., and Demarin, V.I., Radiochemistry, 2015, vol. 57, no. 6, p. 632. https://doi.org/10.1134/S1066362215060119
Pratheep Kumar, S. and Gopal, B., J. Alloys Compd., 2016, vol. 657, p. 422. https://doi.org/10.1016/j.jallcom.2015.10.088
Glogarová, M., Phys. Status Solidi (A), 1974, vol. 22, no. 1, p. 69. https://doi.org/10.1002/pssa.2210220159
Hikita, T., Kitabatake, M., and Ikeda, T., J. Phys. Soc. Japan, 1980, vol. 49, no. 4, p. 1421. https://doi.org/10.1143/JPSJ.49.1421
Trussov, I.A., Male, L.L., Sanjuan, M.L., Orera, A., and Slater, P.R., J. Solid State Chem., 2019, vol. 272, p. 157. https://doi.org/10.1016/j.jssc.2019.02.014
Zaripov, A.R., Orlova, V.A., Pet’kov, V.I., Slyunchev, O.M., Galuzin, D.D., and Rovnyi, S.I., Russ. J. Inorg. Chem., 2009, vol. 54, p. 45 https://doi.org/10.1134/S0036023609010112
Pet’kov, V.I., Alekseev, A.A., Asabina, E.A., Borovikova, E.Y., and Koval’ski, A.M., Russ. J. Inorg. Chem., 2017, vol. 62, no. 7, p. 870 https://doi.org/10.1134/S0036023617070178
Filatov, S.K., Vysokotemperaturnaya kristallokhimiya. Teoriya, metody i rezul’taty issledovanii (High Temperature Crystal Chemistry. Theory, Methods, and Research Results), Leningrad: Nedra, 1990.
Krivovichev, S.V. and Filatov, S.K., Kristallokhimiya mineralov i neorganicheskikh soedinenii s kompleksami anionotsentrirovannykh tetraedrov (Crystal Chemistry of Minerals and Inorganic Compounds with Complexes of Anion-Centered Tetrahedra), St. Petersburg: SPbGU, 2001.
Rietveld, H.M., Acta Crystallogr., 1967, vol. 22, no. 1, p. 151. https://doi.org/10.1107/S0365110X67000234
Kim, Y.I. and Izumi, F., J. Ceram. Soc. Japan, 1994, vol. 102, p. 401. https://doi.org/10.2109/jcersj.102.401
Izumi, F., The Rietveld Method, New York: Oxford University Press, 1993, ch. 13, p. 236. https://doi.org/10.1002/crat.2170300412
Leclaire, A., Benmoussa, A., Borel, M.M., Grandin, A., and Raveau, B., J. Solid State Chem., 1989, vol. 78, p. 227. https://doi.org/10.1016/0022-4596(89)90101-1
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This study was financially supported by the Russian Foundation for Basic Research (project no. 18-29-12063).
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Pet’kov, V.I., Alekseev, A.A., Asabina, E.A. et al. New Formula Type of Phosphates with Langbeinite Mineral Structure. Russ J Gen Chem 90, 680–685 (2020). https://doi.org/10.1134/S1070363220040192
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DOI: https://doi.org/10.1134/S1070363220040192