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Synthesis and Electronic Transitions of the Dye Based on 1-{2-[4-(3-Hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium Bromide

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Abstract

4-[4-(2-Bromoacetyl)phenyl]-3-hydroxy-2H-chromen-2-one reacted with pyridine and 4-methylpyridine to give the corresponding quaternary pyridinium salts. The condensation of 1-{2-[4-(3-hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium bromide with 4-(dimethylamino)benzaldehyde afforded a new biscyanine dye whose electronic spectrum showed two absorption maxima originating from interactions of chromophores. The nature of electronic transitions in the dye molecule was analyzed by quantum chemical calculations.

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Authors and Affiliations

  1. Yu. Fedkovych Chernivtsi National University, 58012, Chernivtsi, Ukraine

    O. V. Skrypska, O. V. Rusnak & P. I. Yagodinets

  2. Ivan Franko National University of Lviv, 79005, Lviv, Ukraine

    R. Z. Lytvyn, Kh. Ye. Pitkovych & M. D. Obushak

  3. Ivano-Frankivsk National Medical University, 76018, Ivano-Frankivsk, Ukraine

    D. O. Melnyk

Authors
  1. O. V. Skrypska
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  2. R. Z. Lytvyn
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  3. O. V. Rusnak
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  4. D. O. Melnyk
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  5. Kh. Ye. Pitkovych
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  6. P. I. Yagodinets
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  7. M. D. Obushak
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Correspondence to M. D. Obushak.

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Skrypska, O.V., Lytvyn, R.Z., Rusnak, O.V. et al. Synthesis and Electronic Transitions of the Dye Based on 1-{2-[4-(3-Hydroxy-2-oxo-2H-chromen-4-yl)phenyl]-2-oxoethyl}-4-methylpyridinium Bromide. Russ J Gen Chem 90, 602–609 (2020). https://doi.org/10.1134/S1070363220040076

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