Abstract
Nanocrystalline bismuth titanates Bi2Ti4O11 (115±5 nm), Bi4Ti3O12 (60±5 nm), Bi2Ti2O7 (105±5 nm), Bi8TiO14 (82±5 nm), and Bi12TiO20 (102±5 nm) were synthesized by heat treatment of the coprecipitated composition. It was revealed that the crystallite sizes of the target materials are determined by the minimum crystallite size of the first phase to crystallize in the reaction system. The process parameters of the synthesis and of the sintering of the materials were found to depend on the melting point of the surface (nonautonomous) phase. It was shown that the formation of the materials is mainly influenced by the kinetic factor, and the influence of the structural features is less pronounced.
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Speranskaya, E.I., Rez, I.S., Kozlova, L.V., Skorikov, V.M., and Slavov, V.I., Izv. Akad. Nauk SSSR, Ser. Neorg. Mater., 1965, vol. 1, no. 2, p. 232.
Lu, C.-D., Chang, L.-S., Lu, Y.-F., and Lu, F.-H., Ceram. Int., 2009, vol. 35, p. 2699. https://doi.org/10.1016/j.ceramint.2009.03.001
Esquivel-Elizondo, J.R., Hinojosa, B.B., and Nino, J.C., Chem. Mater., 2011, vol. 23, p. 4965. https://doi.org/10.1021/cm202154c
Lopez-Martinez, J., Romero-Serrano, A., Hernandez-Ramirez, A., Zeifert, B., Gomez-Yanez, C., and Martinez-Sanchez, R., Thermochim. Acta, 2011, vol. 516, p. 35. https://doi.org/10.1016/j.tca.2011.01.008
Bohm, H., J. Eur. Ceram. Soc., 2007, vol. 27, nos. 3–4, p. 887. https://doi.org/10.1016/j.jeurceramsoc.2006.04.059
Zhang, Y., Zhang, Y., Fu, B., Hong, M., and Xiang, M., Ceram. Int., 2015, vol. 41, p. 10243. https://doi.org/10.1016/j.ceramint.2015.04.137
Fu, B., Zhang, Y., Hong, M., Jiang, F., and Cao, J., J. Mater. Sci., 2013, vol. 24, p. 3240. https://doi.org/10.1007/s10854-013-1234-y
Aurrivillius, B., Ark. Kemi, 1949, vol. 1, no. 1, p. 463.
Joung, M.R., Jeong, B.-J., Kim, J.-S., Woo, S.-R., Park, H.-M., and Nahm, S., J. Am. Ceram. Soc., 2014, vol. 97, p. 2491. https://doi.org/10.1111/jace.12959
Radaev, S.F. and Simonov, V.I., Kristallografiya, 1992, vol. 37, p. 914.
Sarin, V.A., Rider, E.E., Kanepit, V.N., Bydanov, N.N., Volkov, V.V., Kargin, Yu.F., and Skorikov, V.M., Kristallografiya, 1989, vol. 34, p. 628.
Hector, A.L. and Wiggin, S.B., J. Solid State Chem., 2004, vol. 177, p. 139. https://doi.org/10.1016/S0022-4596(03)00378-5
Kahlenberg, V. and Bohm, H., J. Alloys Compd., 1995, vol. 223, p. 142. https://doi.org/10.1107/S0108768194004386
Watanabe, T., Kojima, T., Sakai, T., Funakubo, H., Osada, M., Noguchi, Y., and Miyayama, M., J. Appl. Phys., 2002, vol. 92, no. 3, p. 1518. https://doi.org/10.1063/1.1491594
Cagnon, J., Boesch, D.S., Finstrom, N.H., Nergiz, S.Z., Keane, S.P., and Stemmer, S., J. Appl. Phys., 2007, vol. 102, p. 044102. https://doi.org/10.1063/1.2769777
Jiang, A.Q., Hu, Z.X., and Zhang, L.D., J. Appl. Phys., 1999, vol. 85, p. 1739. https://doi.org/10.1063/L369340
Toyoda, M. and Payne, D.A., Mater. Lett., 1993, vol. 18, nos. 1–2, p. 84. https://doi.org/10.1016/0167-577X(93)90062-3
Lomanova, N.A., Tomkovich, M.V., Sokolov, V.V., and Ugolkov, V.L., Russ. J. Gen. Chem., 2018, vol. 88, no. 12, p. 2459. https://doi.org/10.1134/S1070363218120010
Morozov, M.I., Mezentseva, L.P., and Gusarov, V.V., Russ. J. Gen. Chem., 2002, vol. 72, no. 7, p. 1038. https://doi.org/10.1023/A:1020734312307
Fu, B.J., Zhang, Y.C., Hong, M., Jiang, F., and Cao, J.L., J. Mater. Sci., 2013, vol. 24, p. 3240. https://doi.org/10.1007/s10854-013-1234-y
Zhou, J., Zou, Zh., Ray, A.K., and Zhao, X.S., Ind. Eng. Chem. Res., 2007, vol. 46, no. 3, p. 745. https://doi.org/10.1021/ie0613220
Lomanova, N.A., Morozov, M.I., Ugolkov, V.L., and Gusarov, V.V., Russ. J. Inorg. Mater., 2006, vol. 42, no. 2, p. 189. https://doi.org/10.1134/S0020168506020142
Zhang, Y., Zhang, Y., Fu, B., Hong, M., and Xiang, M., Ceram. Int., 2015, vol. 41, p. 10243. https://doi.org/10.1016/j.ceramint.2015.04.137
Knop, O. and Brisse, F., Can. J. Chem., 1969, vol. 47, p. 971. https://doi.org/10.1139/v69-155#.W1cjMMLWi70
Kolesnik, I.V., Lebedev, V.A., and Garshev, A.V., Nanosyst.: Phys. Chem. Math., 2018, vol. 9, no. 3, p. 401. https://doi.org/10.17586/2220-8054-2018-9-3-401-409
Hou, Y., Wang, M., Xu, X.H., Wang, D., Wang, H., and Shang, S.X., J. Am. Ceram. Soc., 2002, vol. 85, p. 3087. https://doi.org/10.1111/j.1151-2916.2002.tb00585.x
Lomanova, N.A., Tomkovich, M.V., Ugolkov, V.L., and Gusarov, V.V., Russ. J. Appl. Chem., 2017, vol. 90, no. 6, p. 831. https://doi.org/10.1134/S1070427217060015
Valeeva, A.A. and Kostenko, M.G., Nanosyst.: Phys., Chem., Math., 2016, vol. 8, no. 6, p. 816. https://doi.org/10.17586/2220-8054-2017-8-6-816-822
Almjasheva, O.V., Nanosyst.: Phys., Chem., Math., 2016, vol. 7, no. 6, p. 1031. https://doi.org/10.17586/2220-8054-2016-7-6-1031-1049
Ivicheva, S.N., Kargin, Yu F., Kutsev, S.V., and Ashmarin, A.A., Russ. J. Inorg. Chem., 2015, vol. 60, no. 11, p. 1317. https://doi.org/10.1134/S003602361511008X
Bespalova, Zh.I. and Khramenkova, A.V., Nanosyst.: Phys., Chem., Math., 2016, vol. 7, no. 3, p. 433. https://doi.org/10.17586/2220-8054-2016-7-3-433-450
Almjasheva, O.V. and Gusarov, V.V., Russ. J. Gen. Chem., 2010, vol. 80, no. 3, p. 385. https://doi.org/10.17586/2220-8054-2018-9-5-641-662
Kovalenko, A.N. and Tugova, E.A., Nanosyst.: Phys., Chem., Math., 2018, vol. 9, no. 5, p. 641. https://doi.org/10.1134/S0012501609020031
Almjasheva, O.V., Lomanova, N.A., Popkov, V.I., Proskurina, O.V., Tugova, E.A., and Gusarov, V.V., Nanosyst.: Phys., Chem., Math., 2019, vol. 10, no. 4, p. 428. https://doi.org/10.17586/2220-8054-2019-10-4-428-437
Lomanova, N.A. and Gusarov, V.V., Russ. J. Gen. Chem., 2013, vol. 83, no. 12, p. 2251. https://doi.org/10.1134/S1070363213120049
Lomanova, N.A. and Gusarov, V.V., Nanosyst.: Phys., Chem., Math., 2013, vol. 4, no. 5, p. 696.
Gusarov, V.V. and Suvorov, S.A., Russ. J. Appl. Chem., 1990, vol. 63, no. 8, p. 1479.
Gusarov, V.V., Thermochim. Acta, 1995, vol. 256, no. 2, p. 467. https://doi.org/10.1016/0040-6031(94)01993-Q
Gusarov, V.V., Russ. J. Gen. Chem., 1997, vol. 67, no. 12, p. 1846. https://doi.org/1070-3632/97/6712-1846.
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This study was financially supported by the Russian Science Foundation (project no. 16-13-10252).
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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 10, pp. 1587–1594.
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Lomanova, N.A., Tomkovich, M.V., Osipov, A.V. et al. Synthesis of Nanocrystalline Materials Based on the Bi2O3-TiO2 System. Russ J Gen Chem 89, 2075–2081 (2019). https://doi.org/10.1134/S1070363219100141
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DOI: https://doi.org/10.1134/S1070363219100141