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Colloid and Nanosized Catalysts in Organic Synthesis: XXII. Hydrogenation of Cycloolefins Catalyzed by Immobilized Transition Metals Nanoparticles in a Three-Phase System

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Abstract

The processes of unsaturated cyclic hydrocarbons hydrogenation in a three-phase gas-liquid-solid catalyst system in the presence of nanostructured nickel, cobalt, or iron catalysts in a flow reactor at 130°C and atmospheric pressure have studied. RX3Extra activated carbon, γ-Al2O3, NaX zeolite, and Purolite CT-175 cation-exchange resin have been used as supports; NaBH4 and NH2NH2·H2O were used as reducing agents. The catalytic activity of supported nanoparticles and their selectivity with respect to the product of exhaustive hydrogenation have been investigated.

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Funding

This study was financially supported by the Russian Foundation for Basic Research (project 18-33-00183).

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    D. N. Nebykov, Yu. V. Popov, V. M. Mokhov, S. E. Latyshova, K. V. Shcherbakova, N. V. Nemtseva & E. V. Shishkin

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  1. D. N. Nebykov
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  2. Yu. V. Popov
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  3. V. M. Mokhov
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  4. S. E. Latyshova
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  5. K. V. Shcherbakova
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  6. N. V. Nemtseva
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  7. E. V. Shishkin
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Corresponding author

Correspondence to D. N. Nebykov.

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No conflict of interest was declared by the authors.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 10, pp. 1479–1485.

For communication XXI, see [1]

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Nebykov, D.N., Popov, Y.V., Mokhov, V.M. et al. Colloid and Nanosized Catalysts in Organic Synthesis: XXII. Hydrogenation of Cycloolefins Catalyzed by Immobilized Transition Metals Nanoparticles in a Three-Phase System. Russ J Gen Chem 89, 1985–1989 (2019). https://doi.org/10.1134/S1070363219100013

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