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Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands

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Abstract

Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional aggregates with a regular architecture, whereas the choice of alkynyl ligands determines their luminescent properties.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7-9, St. Petersburg, 199034, Russia

    E. V. Grachova

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Correspondence to E. V. Grachova.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 6, pp. 879–892.

Funding

This work was financially supported by the Russian Scientific Foundation (grant no. 16-13-10064) with the use of equipment of the Scientific park of St. Petersburg state university and also of the Analytical center of nano- and biotechnologies of St. Petersburg polytechnic university.

Conflict of Interest

No conflict of interest was declared by the authors.

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Grachova, E.V. Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands. Russ J Gen Chem 89, 1102–1114 (2019). https://doi.org/10.1134/S1070363219060045

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