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Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

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Abstract

The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7-9, St. Petersburg, 199034, Russia

    M. Yu. Skripkin, L. V. Chernykh, O. N. Pestova, V. E. Baranauskaite, K. A. Burkov, I. V. Zamyatin, L. V. Stepakova, I. M. Gusev, A. O. Gorbunov, N. A. Bogachev & G. L. Starova

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  1. M. Yu. Skripkin
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  2. L. V. Chernykh
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  3. O. N. Pestova
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  4. V. E. Baranauskaite
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  6. I. V. Zamyatin
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  7. L. V. Stepakova
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  11. G. L. Starova
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Corresponding author

Correspondence to M. Yu. Skripkin.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 6, pp. 860–878.

Funding

This work was financially supported by the Russian Foundation for Basic Research (project no. 18-3300636) with the use of equipment of the resource centers “Research Centre for X-ray Diffraction Studies,” “Center for Optical and Laser Materials Research,” “Center for Thermogravimetric and Calorirnetric Research,” and “Center for chemical analysis and materials research” of St. Petersburg State University.

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No conflict of interest was declared by the authors.

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Skripkin, M.Y., Chernykh, L.V., Pestova, O.N. et al. Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems. Russ J Gen Chem 89, 1085–1101 (2019). https://doi.org/10.1134/S1070363219060033

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