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Synthesis and Structure of Platinum Diethyl Sulfoxide Complexes

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Abstract

The reaction of tetraorganylphosphonium and tetraethylammonium chlorides with hexachloroplatinic acid hydrate in a mixture of acetonitrile and diethyl sulfoxide produced [Ph3PEt][PtCl5(deso-S)] and [Et4N][PtCl5(deso-S)] complexes containing tetrahedral tetraorganylphosphonium or tetraethylammonium cations and octahedral diethylsulfoxidopentachloroplatinate anions.

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Authors and Affiliations

  1. National Research South Ural State University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    A. R. Tkacheva, V. V. Sharutin & O. K. Sharutina

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  1. A. R. Tkacheva
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  2. V. V. Sharutin
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  3. O. K. Sharutina
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Correspondence to A. R. Tkacheva.

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Russian Text © A.R. Tkacheva, V.V. Sharutin, O.K. Sharutina, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 2, pp. 283–287.

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Tkacheva, A.R., Sharutin, V.V. & Sharutina, O.K. Synthesis and Structure of Platinum Diethyl Sulfoxide Complexes. Russ J Gen Chem 89, 277–280 (2019). https://doi.org/10.1134/S107036321902018X

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  • DOI: https://doi.org/10.1134/S107036321902018X

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