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Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides

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Abstract

An effective method was developed for the synthesis of acyclic aniline derivatives bearing carbamide fragments by the reaction of carbamides with ortho-, meta-, and para-aminobenzamides and bis(N,N-dimethylamino) methane in the presence of NiCl2·6H2O and SmCl3·6H2O as catalysts.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    R. R. Khairullina, T. V. Tyumkina, A. R. Geniyatova, F. K. Mullagil’dina & A. G. Ibragimov

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  1. R. R. Khairullina
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  2. T. V. Tyumkina
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  3. A. R. Geniyatova
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  4. F. K. Mullagil’dina
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  5. A. G. Ibragimov
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Correspondence to R. R. Khairullina.

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Russian Text © R.R. Khairullina, T.V. Tyumkina, A.R. Geniyatova, F.K. Mullagil’dina, A.G. Ibragimov, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 2, pp. 202–210.

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Khairullina, R.R., Tyumkina, T.V., Geniyatova, A.R. et al. Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides. Russ J Gen Chem 89, 204–211 (2019). https://doi.org/10.1134/S1070363219020063

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  • DOI: https://doi.org/10.1134/S1070363219020063

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