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Synthesis and Structure of μ2-Oxobis(carboxylatotriarylantimony)

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Abstract

Binuclear antimony compounds with a bridging oxygen atom [Ph3SbOC(O)R]2O (R = CF2CF3, CF2CF2CF3), [(4-МеC6H4)3SbOC(O)CF2CF3]2O, [(3-FC6H4)3SbOC(O)R]2O (R = C6F5, CF2CF3) have been synthesized by reacting equimolar amounts of triarylantimony, carboxylic acid and tert-butyl hydroperoxide in diethyl ether. According to X-ray diffraction data, in the molecules of compounds obtained, the Sb atoms have a trigonal bipyramid coordination with carboxylate ligands and a bridging oxygen atom in axial positions. The intramolecular distances Sb···O with a carbonyl oxygen atom are less than the sum of the van der Waals radii of Sb and O by ~0.2–0.4 Å.

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Authors and Affiliations

  1. National Research South Ural State University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, A. N. Efremov & E. V. Artem’eva

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. N. Efremov
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  4. E. V. Artem’eva
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Correspondence to V. V. Sharutin.

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Russian Text © V.V. Sharutin, O.K. Sharutina, A.N. Efremov, E.V. Artem’eva, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 1, pp. 89–94.

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Sharutin, V.V., Sharutina, O.K., Efremov, A.N. et al. Synthesis and Structure of μ2-Oxobis(carboxylatotriarylantimony). Russ J Gen Chem 89, 76–81 (2019). https://doi.org/10.1134/S1070363219010146

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  • DOI: https://doi.org/10.1134/S1070363219010146

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