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Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide

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Abstract

Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.

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Correspondence to A. S. Mikherdov.

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Dedicated to the 115th anniversary of B.A. Arbuzov’s birth

Original Russian Text © R.A. Popov, A.S. Novikov, A.S. Mikherdov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 11, pp. 1871–1877.

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Popov, R.A., Novikov, A.S. & Mikherdov, A.S. Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide. Russ J Gen Chem 88, 2347–2353 (2018). https://doi.org/10.1134/S1070363218110166

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