Russian Journal of General Chemistry

, Volume 88, Issue 4, pp 797–803 | Cite as

Preparation and Spectroscopic Studies of Charge-Transfer Complexes of Thiamine Hydrochloride with Different Electron Acceptor

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Abstract

Abstract—Electronic interactions associated with charge transfer complexes formation of iodine, chloranilic acid (H2CA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) with vitamin B1 have been studied spectrophotometrically. The accumulated data indicated formation of CT-complexes of the general formula [(VB1)(acceptor) n ], (n = 1 or 2). The 1 : 2 and 1 : 1 donor: acceptor molar ratios were calculated on the basis of elemental analysis and photometric titrations. The solid complexes were prepared and characterized by their conductivity, UV-Vis, IR, and 1H NMR spectra, and thermogravimetric analyses (TGA, DTG). The characteristic physical constants (KCT, εCT, μ, ΔG, Ip, f, ECT) of the formed CT-complexes were determined to be strongly dependent on nature of the electron acceptors.

Keywords

charge-transfer vitamin B1 iodine H2CA DDQ UV-Vis IR 1H NMR TGA DTG 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Chemistry Department, Faculty of ScienceZagazig UniversityZagazigEgypt
  2. 2.Faculty of Specific EducationZagazig UniversityZagazigEgypt

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