Abstract
Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).
Similar content being viewed by others
References
Bielawski, C.W. and Grubbs, R.H., Progr. Polym. Sci., 2007, vol. 32, p. 1. doi 10.1016/j.progpolymsci.2006.08.006
Leitgeb, A., Wappel, J., and Slugovc, C., Polymer, 2010, vol. 51, p. 2927. doi 10.1016/j.polymer.2010.05.002
Zaquen, N., Lutsen, L., Vanderzande, D., and Junkers, T., Polym. Chem., 2016, vol. 7, p. 1355. doi 10.1039/c5py01987g
Feng, K., Zuniga, C., Zhang, Y.-D., Kim, D., Barlow, S., Marder, S.R., and Brédas, J.L., Weck, M., Macromolecules, 2009, vol. 42, p. 6855. doi 10.1021/ma901280x
Bochkarev, L.N., Begantsova, Yu.E., Il’ichev, V.A., and Abakumov, G.A., Russ. Chem. Bull., 2014, vol. 63, no. 11, p. 2534. doi 10.1007/s11172-014-07
Kimyonok, A., Domercq, B., Haldi, A., Cho, J.-Y., Carlise, J.R., Wang, X.-Y., Hayden, L.E., Jones, S.C., Barlow, S., Marder, S.R., Kippelen, B., and Weck, M., Chem. Mater., 2007, vol. 19, p. 5602. doi 10.1021/cm0717357
Lai, W.-Y., Balfour, M.N., Levell, J.W., Bansal, A.K., Burn, P.L., Lo, S.-C., and Samuel, I.D.W., Macromolecules, 2012, vol. 45, p. 2963. doi 10.1021/ma300306d
Bochkarev, L.N., Begantsova, Yu.E., Platonova, E.O., Basova, G.V., Rozhkov, A.V., Il’ichev, V.A., Baranov, E.V., Abakumov, G.A., and Bochkarev, M.N., Russ. Chem. Bull., 2014, vol. 63, no. 4, p. 1001. doi 10.1007/s11172-014-05
Platonova, E.O., Il’ichev, V.A., Baranov, E.V., and Bochkarev, L.N., Russ. J. Coord. Chem., 2016, vol. 42, no. 3, p. 187. doi 10.1134/S1070328416030076
Rao, N.V., Ganivada, M.N., Sarkar, S., Dinda, H., Chatterjee, K., Dalui, T., Das Sarma, J., and Shunmugam, R., Bioconjugate Chem., 2014, vol. 25, p. 276. doi 10.1021/bc400409n
Shao, Y., Jia, Y.-G., Shi, C., Luo, J., and Zhu, X.X., Biomacromolecules, 2014, vol. 15, p. 1837. doi 10.1021/bm5002262
Tezgel, A.Ö., Telfer, J.C., and Tew, G.N., Biomacromolecules, 2011, vol. 12, p. 3078. doi 10.1021/bm200694u
Gueugnon, F., Denis, I., Pouliquen, D., Collette, F., Delatouche, R., Heroguez, V., Gregoire, M., Bertrand, P., and Blanquart, C., Biomacromolecules, 2013, vol. 14, p. 2396. doi 10.1021/bm400516b
Lo, K.K.-W., Li, S.P.-Y., and Zhang, K.Y., New J. Chem., 2011, vol. 35, p. 265. doi 10.1039/c0nj00478b
Baggaley, E., Weinstein, J.A., and Williams, J.A.G., Coord. Chem. Rev., 2012, vol. 256, p. 1762. doi 10.1016/j.ccr.2012.03.018
Hersey, J.S., Meller, A., and Grinstaff, M.W., Anal. Chem., 2015, vol. 87, p. 11863. doi 10.1021/acs.analchem.5b03386
Begantsova, Yu.E., Bochkarev, L.N., Samsonov, M.A., and Fukin, G.K., Russ. J. Coord. Chem., 2013, vol. 39, no. 9, p. 661. doi 10.1134/S1070328413090017
Bochkarev, L.N., Begantsova, Yu.E., Il’ichev, V.A., Baranov, E.V., Abakumov, G.A., Russ. J. Coord. Chem., 2015, vol. 41, no. 9, p. 555. doi 10.1134/S1070328415090018
Montalti, M., Credi, A., Prodi, L., and Gandolfi, M.T., Handbook of Photochemistry, Boca Raton, FL: CRC Press, 2006, 3rd ed.
Scholl, M., Ding, S., Lee, C.W., and Grubbs, R.H., Org. Lett., 1999, vol. 1, p. 953. doi 10.1021/ol990909q
Love, J.A., Morgan, J.P., Trnka, T.M., and Grubbs, R.H., Angew. Chem. Int. Ed., 2002, vol. 41, p. 4035. doi 10.1002/1521-3773(20021104)41:21<4035::AIDANIE4035> 3.0.CO;2-I
Magde, D., Wong, R., and Seybold, P.G., Photochem. Photobiol., 2002, vol. 75, p. 327. doi 10.1562/0031-8655(2002)0750327FQYATR2.0.CO2
Lуpez Arbeloa, F., Ruiz Ojeda, P., and Lуpez Arbeloa, I., J. Lumin., 1989, vol. 44, p. 105. doi 10.1016/0022-2313 (89)90027-6
Demas, J.N. and Crosby, G.A., J. Phys. Chem., 1971, vol. 75, p. 991. doi 10.1021/j100678a001
Freshney, M.G., Culture of Immortalized Cells, New York: Wiley-Liss, 2010.
Acknowledgments
This study was financially supported by the Russian Foundation for Basic Research (project nos. 15-43-02178-r_povolzh’e_a, 16-33-0234-mol_a, 16-34-60117-mol_a_dk).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.O. Platonova, A.V. Rozhkov, S.A. Lermontova, L.G. Klapshina, A.N. Konev, L.N. Bochkarev, G.A. Abakumov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 4, pp. 650–654.
Rights and permissions
About this article
Cite this article
Platonova, E.O., Rozhkov, A.V., Lermontova, S.A. et al. Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties. Russ J Gen Chem 88, 731–735 (2018). https://doi.org/10.1134/S1070363218040175
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363218040175