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Russian Journal of General Chemistry

, Volume 88, Issue 4, pp 632–640 | Cite as

Solvent Effect on the Rate of Thermal Decomposition of Diacyl Diperoxides

  • V. S. Dutka
  • G. G. Midyana
  • E. Ya. Pal’chikova
  • Yu. V. Dutka
Article
  • 4 Downloads

Abstract

The kinetics of thermal decomposition of didecanoyl diperoxyadipate in different organic solvents have been studied. The primary homolytic dissociation of the peroxide bond (O–O) is accompanied by secondary induced chain decomposition processes. The reaction medium affects both the rate of primary homolytic decomposition and secondary decomposition processes. Correlation equations have been proposed for the rate constants of the reactions under study and physicochemical parameters of the solvents.

Keywords

diperoxides rate constants of thermal decomposition solvent effect energy of activation correlation equations 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. S. Dutka
    • 1
  • G. G. Midyana
    • 2
  • E. Ya. Pal’chikova
    • 3
  • Yu. V. Dutka
    • 1
  1. 1.Іvan Franko National University of LvivLvivUkraine
  2. 2.Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal ChemistryNational Academy of Sciences of UkraineLvivUkraine
  3. 3.Institute of Geology and Geochemistry of Fossil FuelsNational Academy of Sciences of UkraineLvivUkraine

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