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Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents

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Abstract

Solubility of copper(II) chloride at 25°C in binary organic solvents consisting of dimethyl sulfoxide, N,N-dimethylacetamide, and 1,4-dioxane was determined by the isothermal saturation method. The shape of solubility isotherms for all ternary systems under study is connected with the structural type of formed copper chloride solvates, the composition of which is defined by the solvent donor number. Solvates crystallize predominantly, where the metal ion coordinates molecules of the solvent with a greater donor power. The temperature increase in the system CuCl2–dimethylacetamide–dioxane up to 50°C leads to the formation of the cluster compound [Cu4Cl6O(DMA)4]; its structure was determined by the X-ray structural analysis method.

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Acknowledgments

This work was financially supported by the Russian Foundation for basic research (project no. 15-03- 05139). The equipment of the St. Petersburg State University Research Center “X-ray diffraction research methods” was used.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    N. A. Bogachev, D. A. Lyubichev, G. L. Starova, A. B. Nikolskii & M. Yu. Skripkin

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  1. N. A. Bogachev
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  2. D. A. Lyubichev
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  3. G. L. Starova
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  4. A. B. Nikolskii
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  5. M. Yu. Skripkin
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Correspondence to N. A. Bogachev.

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Original Russian Text © N.A. Bogachev, D.A. Lyubichev, G.L. Starova, A.B. Nikolskii, M.Yu. Skripkin, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 4, pp. 529–533.

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Bogachev, N.A., Lyubichev, D.A., Starova, G.L. et al. Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents. Russ J Gen Chem 88, 617–621 (2018). https://doi.org/10.1134/S1070363218040011

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  • DOI: https://doi.org/10.1134/S1070363218040011

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