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Russian Journal of General Chemistry

, Volume 88, Issue 3, pp 596–597 | Cite as

Energy Characteristics of Lithium–Cesium Binary Chloride Dissolution in Water

  • O. N. Pestova
  • V. A. Bukesova
  • Yu. V. Kondrat’ev
  • V. D. Khripun
  • V. E. Baranauskaite
Letters to the Editor
  • 8 Downloads

Abstract

Enthalpies of dissolution of the binary salt LiCl·3CsCl·4H2O and dry mixtures of lithium and cesium chlorides in the molar ratio 1: 3 were measured by the calorimetry method. The value of the mutual influence of ions in solution was determined, and the enthalpy of the binary salt formation from the individual components was calculated.

Keywords

enthalpy of dissolution calorimetry lithium-cesium binary chloride mutual influence of ions 

References

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    Spravochnik eksperimental’nykh dannykh po rastvorimosti mnogokomponentnykh vodno-solevykh sistem (Handbook of Experimental Data on the Solubility of Multicomponent Water-Salt Systems), Pel’sh A.D., Ed., vol. I-1, Leningrad: Khimiya, 1973, p. 51.Google Scholar
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    Pestova, O.N., Baranauskaite, V.E., and Khripun, M.K., Russ. J. Gen. Chem., 2016, vol. 86, no. 4, p. 767. doi 10.1134/S1070363216040010CrossRefGoogle Scholar
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    Thermal Constants of Substances, database www.chem.msu.su.Google Scholar
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    Golubev, B.A., Kondrat’ev, Yu.v., and Sheitel’man, B.I., USSR Inventor’s Certificate no. 1283553, 1985.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • O. N. Pestova
    • 1
  • V. A. Bukesova
    • 1
  • Yu. V. Kondrat’ev
    • 1
  • V. D. Khripun
    • 1
  • V. E. Baranauskaite
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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