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Russian Journal of General Chemistry

, Volume 88, Issue 3, pp 495–499 | Cite as

Novel Mixed Complexes of Copper(II) and Ethylenediamine: Synthesis, Crystal Structure, and Catalytic Activity in the Cross-Coupling Reaction of 1-Phenyl-5H-tetrazole-5-thiol and Iodobenzene

  • L. V. Myznikov
  • A. I. Fisher
  • U. N. Dmitrieva
  • T. V. Artamonova
  • Yu. E. Zevatskii
Article

Abstract

Two earlier unknown complexes, [Cu(en)2(Hptt)]Br (Hptt = 1-phenyl-1H-terazole-5-thiol, en = ethylenediamine) and trans-[Cu(en)2(H2O)Br]Br, have been synthesized and characterized using X-ray diffraction analysis. In [Cu(en)2(Hptt)]Br complex, the copper cation is bonded with the N4 atom of tetrazole ring. Catalytic activity of the obtained complexes in cross-coupling reaction of 1-phenyl-5H-tetrazole-5-thiol with iodobenzene is comparable to that of CuBr2 in the presence of 2 eq. of ethylenediamine.

Keywords

copper ethylenediamine 1-phenyltetrazole-5-thiol complex compound X-ray diffraction analysis catalysis 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. V. Myznikov
    • 1
  • A. I. Fisher
    • 2
  • U. N. Dmitrieva
    • 1
  • T. V. Artamonova
    • 1
  • Yu. E. Zevatskii
    • 1
    • 3
  1. 1.St. Petersburg State University of Industrial Technologies and DesignSt. PetersburgRussia
  2. 2.St. Petersburg State Technological Institute (Technical University)St. PetersburgRussia
  3. 3.V.I. Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI”St. PetersburgRussia

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