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Novel Mixed Complexes of Copper(II) and Ethylenediamine: Synthesis, Crystal Structure, and Catalytic Activity in the Cross-Coupling Reaction of 1-Phenyl-5H-tetrazole-5-thiol and Iodobenzene

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Abstract

Two earlier unknown complexes, [Cu(en)2(Hptt)]Br (Hptt = 1-phenyl-1H-terazole-5-thiol, en = ethylenediamine) and trans-[Cu(en)2(H2O)Br]Br, have been synthesized and characterized using X-ray diffraction analysis. In [Cu(en)2(Hptt)]Br complex, the copper cation is bonded with the N4 atom of tetrazole ring. Catalytic activity of the obtained complexes in cross-coupling reaction of 1-phenyl-5H-tetrazole-5-thiol with iodobenzene is comparable to that of CuBr2 in the presence of 2 eq. of ethylenediamine.

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Authors and Affiliations

  1. St. Petersburg State University of Industrial Technologies and Design, ul. Bol’shaya Morskaya 18, St. Petersburg, 191186, Russia

    L. V. Myznikov, U. N. Dmitrieva, T. V. Artamonova & Yu. E. Zevatskii

  2. St. Petersburg State Technological Institute (Technical University), St. Petersburg, Russia

    A. I. Fisher

  3. V.I. Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI”, St. Petersburg, Russia

    Yu. E. Zevatskii

Authors
  1. L. V. Myznikov
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  2. A. I. Fisher
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  3. U. N. Dmitrieva
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  4. T. V. Artamonova
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  5. Yu. E. Zevatskii
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Correspondence to L. V. Myznikov.

Additional information

Original Russian Text © L.V. Myznikov, A.I. Fisher, U.N. Dmitrieva, T.V. Artamonova, Yu.E. Zevatskii, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 3, pp. 468–472.

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Myznikov, L.V., Fisher, A.I., Dmitrieva, U.N. et al. Novel Mixed Complexes of Copper(II) and Ethylenediamine: Synthesis, Crystal Structure, and Catalytic Activity in the Cross-Coupling Reaction of 1-Phenyl-5H-tetrazole-5-thiol and Iodobenzene. Russ J Gen Chem 88, 495–499 (2018). https://doi.org/10.1134/S1070363218030155

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  • DOI: https://doi.org/10.1134/S1070363218030155

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