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Vanadium-Catalyzed Condensation of Ethyl Cyanoacetate with Ketones

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Abstract

Vanadium compounds and complexes activated by pyridine or morpholine catalyze condensation of ethyl cyanoacetate with ketones and aldehydes leading to alkylidenecyanoacetates in 75–100% yield.

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Correspondence to R. I. Khusnutdinov.

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Original Russian Text © R.I. Khusnutdinov, N.А. Shchadneva, Yu.Yu. Mayakova, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 3, pp. 375–381.

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Khusnutdinov, R.I., Shchadneva, N.А. & Mayakova, Y.Y. Vanadium-Catalyzed Condensation of Ethyl Cyanoacetate with Ketones. Russ J Gen Chem 88, 403–409 (2018). https://doi.org/10.1134/S1070363218030052

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  • DOI: https://doi.org/10.1134/S1070363218030052

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