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Reactions of Dichloroethenes with Sulfur in the System Hydrazine Hydrate–KОН

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Abstract

Vinylidene chloride and 1,2-dichloroethene react with sulfur in the system hydrazine hydrate–KОН with the formation of polyvinylenesulfide oligomer of molecular mass 1750–6120 Da containing also vinylenehydrazine and vinylenechloride links in the Z-configuration, and 1,4-dithiine in the yield up to 46%. In aqueous-hydrazine layer polysulfide anions S n 2– (n = 1–4), mainly S22– were found. The mechanism of formation of oligomers and 1,4-dithiine is suggested, which includes in the first stage dehydrochlorination of dichloroethenes and generation of chloroacetylene.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    Е. P. Levanova, V. S. Nikonova, V. А. Grabel’nykh, N. V. Russavskaya, A. I. Albanov, I. B. Rozentsveig & N. А. Korchevin

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  1. Е. P. Levanova
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  2. V. S. Nikonova
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  3. V. А. Grabel’nykh
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  4. N. V. Russavskaya
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  5. A. I. Albanov
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  6. I. B. Rozentsveig
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  7. N. А. Korchevin
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Corresponding author

Correspondence to V. А. Grabel’nykh.

Additional information

Original Russian Text © Е.P. Levanova, V.S. Nikonova, V.А. Grabel’nykh, N.V. Russavskaya, А.I. Albanov, I.B. Rozentsveig, N.А. Korchevin, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 3, pp. 353–359.

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Levanova, Е.P., Nikonova, V.S., Grabel’nykh, V.А. et al. Reactions of Dichloroethenes with Sulfur in the System Hydrazine Hydrate–KОН. Russ J Gen Chem 88, 383–388 (2018). https://doi.org/10.1134/S1070363218030015

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  • DOI: https://doi.org/10.1134/S1070363218030015

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