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Russian Journal of General Chemistry

, Volume 88, Issue 2, pp 295–304 | Cite as

Features of the Formation of Thin Films of Supersaturated Cd x Pb1–xS Solid Solutions by Chemical Bath Deposition

  • L. N. Maskaeva
  • A. D. Kutyavina
  • V. F. Markov
  • I. V. Vaganova
  • V. I. Voronin
Article

Abstract

Thin nanostructured films of lead sulfide-based CdxPb1–xS solid solutions, strongly supersaturated with respect to the substituting component, were prepared by hydrochemical deposition from ammonia-citrate, ethylenediamine-citrate, and ethylenediamine reaction mixtures onto glass-ceramic substrates. The structure, composition, and morphology of the resulting films were examined. An interesting feature of the synthesis was revealed, a distinct correlation between the linear dimensions of the crystallites constituting the films and the cadmium sulfide content therein: the higher cadmium sulfide content, the smaller were the crystallites.

Keywords

hydrochemical deposition lead sulfide cadmium sulfide supersaturated substitutional solid solutions 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. N. Maskaeva
    • 1
    • 2
  • A. D. Kutyavina
    • 1
  • V. F. Markov
    • 1
    • 2
  • I. V. Vaganova
    • 1
  • V. I. Voronin
    • 3
  1. 1.Yeltsin Ural Federal UniversityYekaterinburgRussia
  2. 2.Ural Institute of State Fire Service of Emercom of RussiaYekaterinburgRussia
  3. 3.Mikheev Institute of Metal Physics, Ural BranchRussian Academy of SciencesYekaterinburgRussia

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