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Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes

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Abstract

The influence of the structure of diimine bridge in the Schiff’s bases (derivatives of N,N'-ethylenebissalicylimine) on the rate of the loss of electroactivity of their complexes with nickel in acetonitrile containing 0.1 M of tetraethylammonium tetrafluoroborate (anhydrous and upon addition of 1 wt % of water) has been studied. It has been shown that the presence of bulky yet light methyl groups in the structure of diimine bridge significantly reduced the loss of electroactivity (37% of the initial capacity retained after 50 cycles) as compared to the ligand containing no substituents and containing phenyl group as the substituent (17 and 20%, respectively, of initial capacity retained after 50 cycles).

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    V. A. Ershov, E. V. Alekseeva, A. S. Konev, N. S. Chirkov, T. A. Stelmashuk & O. V. Levin

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  1. V. A. Ershov
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  2. E. V. Alekseeva
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  3. A. S. Konev
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  4. N. S. Chirkov
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  5. T. A. Stelmashuk
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  6. O. V. Levin
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Correspondence to V. A. Ershov.

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Original Russian Text © V.A. Ershov, E.V. Alekseeva, A.S. Konev, N.S. Chirkov, T.A. Stelmashuk, O.V. Levin, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 2, pp. 300–306.

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Ershov, V.A., Alekseeva, E.V., Konev, A.S. et al. Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes. Russ J Gen Chem 88, 277–283 (2018). https://doi.org/10.1134/S1070363218020147

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