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Features of Sulfonation of Polychlorinated Biphenyl Congeners

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Abstract

Sulfonation of polychlorinated biphenyls (PCBs) and their commercial mixture (Trichlorobiphenyl) with oleum has been studied. General sulfonation patterns have been revealed for PCB congeners having no substituents in the ortho positions. The sulfonation of PCBs with chlorine atoms in only one aromatic ring gives exclusively the corresponding polychlorobiphenylmonosulfonic acids. The sulfonation of PCBs with chlorine atoms in both aromatic rings is accompanied by side formation of polychlorodibenzothiophene S,S-dioxides.

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137, Russia

    K. A. Plotnikova, T. I. Gorbunova, M. G. Pervova, V. I. Saloutin & O. N. Chupakhin

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  1. K. A. Plotnikova
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  2. T. I. Gorbunova
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  3. M. G. Pervova
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  4. V. I. Saloutin
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  5. O. N. Chupakhin
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Correspondence to M. G. Pervova.

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Original Russian Text © K.A. Plotnikova, T.I. Gorbunova, M.G. Pervova, V.I. Saloutin, O.N. Chupakhin, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 2, pp. 279–284.

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Plotnikova, K.A., Gorbunova, T.I., Pervova, M.G. et al. Features of Sulfonation of Polychlorinated Biphenyl Congeners. Russ J Gen Chem 88, 257–261 (2018). https://doi.org/10.1134/S1070363218020111

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  • DOI: https://doi.org/10.1134/S1070363218020111

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