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Pd2+-Catalyzed Addition of 1-Substituted Tetrazole-5-thiols to Terminal Acetylenes in Acid Medium

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Abstract

Addition of 1-substituted tetrazole-5-thiols to ethyl propiolate and phenylacetylene was studied. It was found that Pd(II) salts in the presence of strong acids are effective catalysts for this reaction: the S-adducts can be obtained at relatively low temperatures in high yields. The mechanism of this reaction was suggested.

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Authors and Affiliations

  1. St. Petersburg State University of Industrial Technology and Design, ul. Bolshaya Morskaya 18, St. Petersburg, 191186, Russia

    L. V. Myznikov, Yu. V. Melnikova, T. V. Artamonova & Yu. E. Zevatskii

  2. Herzen State Pedagogical University of Russia, St. Petersburg, Russia

    R. I. Baichurin

  3. Novbytkhim Company, St. Petersburg, Russia

    Yu. V. Melnikova & Yu. E. Zevatskii

Authors
  1. L. V. Myznikov
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  2. Yu. V. Melnikova
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  3. R. I. Baichurin
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  4. T. V. Artamonova
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  5. Yu. E. Zevatskii
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Corresponding author

Correspondence to L. V. Myznikov.

Additional information

Original Russian Text © L.V. Myznikov, Yu.V. Melnikova, R.I. Baichurin, T.V. Artamonova, Yu.E. Zevatskii, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 2, pp. 236–241.

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Myznikov, L.V., Melnikova, Y.V., Baichurin, R.I. et al. Pd2+-Catalyzed Addition of 1-Substituted Tetrazole-5-thiols to Terminal Acetylenes in Acid Medium. Russ J Gen Chem 88, 216–220 (2018). https://doi.org/10.1134/S1070363218020068

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  • DOI: https://doi.org/10.1134/S1070363218020068

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