Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 3097–3101 | Cite as

Study of the Rheological Properties of Aqueous Solutions of Porphyrin Polymers

  • E. V. Alopina
  • T. S. Usacheva
  • T. A. Ageeva
  • O. I. Koifman
Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)

Abstract

The behavior of porphyrin polymers derived from polyvinyl alcohol in aqueous solutions was investigated by viscometry. It was found that increasing amount of porphyrin in the immobilizate increases the size of the macromolecular coil of polyvinyl alcohol due to the incorporation of the tetrapyrrole macroheterocycle into the polymer matrix. It was shown that the immobilized porphyrin structure does not affect the nature of the polymer‒solvent interaction.

Keywords

porphyrin polymer polyvinyl alcohol viscosity water polymer solutions rheological properties 

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References

  1. 1.
    Semchikov, Yu.D., Vysokomolekulyarnye soedineniya (Macromolecular Compounds), Moscow: Akademiya, 2003.Google Scholar
  2. 2.
    Tager, A.A., Fizikokhimiya polimerov (Physical Chemistry of Polymers), Moscow: Khimiya, 1978, 3rd ed., p. 358.Google Scholar
  3. 3.
    Koifman, O.I. and Ageeva, T.A., Porfirinpolimery (Porphyrin Polymers), Moscow: Fiziko-Matematicheskaya Literatura, 2006.Google Scholar
  4. 4.
    Koifman, O.I. and Ageeva, T.A., Vysokomol. Soedin., Ser. C, 2004, vol. 46, no. 12, p. 2187.Google Scholar
  5. 5.
    Govorov, A.G., Korzhenevskii, A.B., Koifman, O.I., and Shikova, T.G., Zh. Fiz. Khim., 1995, vol. 69, no. 10, p. 1776.Google Scholar
  6. 6.
    Nikolaeva, O.I., Kurek, S.S., Ageeva, T.A., and Koifman, O.I., Izv. Vyssh. Ucheb. Zaved. Khim. Khim. Tekhnol., 2004, vol. 47, no. 2, p. 146.Google Scholar
  7. 7.
    Chou, J.-H., Nalwa, H.S., Kosal, M.E., Rakow, N.A., and Suslik, K.S., The Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., New York: Academic, 2000, vol. 6, p. 43.Google Scholar
  8. 8.
    Valles, M.A., Uspekhi khimii porfirinov (Advances of Porphyrin Chemistry), Golubchikov, O.A., Ed., St. Peterburg: Nauchno-Issled. Inst. Khimii Sankt-Peterb. Gos. Univ., 2001, vol. 3, p. 179.Google Scholar
  9. 9.
    Alopina, E.V., Ageeva, T.A., Lyubimtsev, A.V., Kuznetsov, O.Yu., Syrbu, S.A., and Koifman, O.I., Macroheterocycl., 2012, vol. 5, no. 1, p. 76. doi 10.6060/mhc2012.111150aCrossRefGoogle Scholar
  10. 10.
    Alopina, E.V., Ageeva, T.A., Koifman, O.I., Izv. Vyssh. Ucheb. Zaved., Khim. Khim. Tekhnol., 2011, vol. 54, no. 12, p. 81.Google Scholar
  11. 11.
    Kochnev, A.M., Zaikin, A.E., Galibeev, S.S., and Arkhireev, V.P., Fizikokhimiya polimerov (Physical Chemistry of Polymer), Kazan: Fen, 2003, p. 497.Google Scholar
  12. 12.
    Toroptseva, A.M., Belogorodskaya, K.V., and Bondarenko, V.M., Laboratornyi praktikum po khimii i tekhnologii vysokomolekulyarnykh soedinenii (Laboratory Manual on the Chemistry and Technology of Macromolecular Compounds), Nikolaev, A.F., Leningrad: Khimiya, 1972, p. 385.Google Scholar
  13. 13.
    Kireev, V.V., Vysokomolekulyarnye soedineniya (Macromolecular Compounds), Moscow: Yurait, 2013.Google Scholar
  14. 14.
    Usacheva, T.S., Karlyuk, M.V., Mitasova, Yu.V., Ageeva, T.A., and Koifman, O.I., Plast. Massy, 2011, no. 1, p. 22.Google Scholar
  15. 15.
    Usacheva, T.S., Karlyuk, M.V., Ageeva, T.A., and Koifman, O.I., Izv. Vyssh. Ucheb. Zaved., Khim. Khim. Tekhnol., 2012, vol. 55, no. 3, p. 76.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. V. Alopina
    • 1
  • T. S. Usacheva
    • 1
  • T. A. Ageeva
    • 1
  • O. I. Koifman
    • 1
    • 2
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia
  2. 2.Krestov Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussia

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