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Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 3086–3092 | Cite as

Plasticization of Cellulose Nitrate by 4-Nitrophtalic Acid Esters

  • A. E. Golubev
  • A. N. Neshitova
  • P. V. Singin
  • S. A. Kuvshinova
  • V. A. Burmistrov
  • O. I. Koifman
Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)

Abstract

The rheological properties of nitrocellulose solutions in cyclohexanone in the presence of phthalic and 4-nitrophthalic diester plasticizers were studied by rotational viscometry to reveal a behavior similar to that of Newtonian fluids. The activation parameters of the viscous flow regime were calculated. An influence of nitroplasticizers and dibutyl phthalate on the rheology of nitrocellulose was established. The influence of plasticizers on the mechanical properties of nitrocellulose films was discussed.

Keywords

nitrocellulose nitro-substituted plasticizers dibutyl phthalate rheology dynamic viscosity activation entropy of viscous flow physical mechanical properties 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. E. Golubev
    • 1
  • A. N. Neshitova
    • 2
  • P. V. Singin
    • 3
  • S. A. Kuvshinova
    • 2
  • V. A. Burmistrov
    • 2
  • O. I. Koifman
    • 2
    • 4
  1. 1.Research Institute of Polymer MaterialsPermRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia
  3. 3.Ivanovo Research Institute of Film Materials and Synthetic Leather for Technical UsesIvanovoRussia
  4. 4.Krestov Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussia

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