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Plasticization of Cellulose Nitrate by 4-Nitrophtalic Acid Esters

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The rheological properties of nitrocellulose solutions in cyclohexanone in the presence of phthalic and 4-nitrophthalic diester plasticizers were studied by rotational viscometry to reveal a behavior similar to that of Newtonian fluids. The activation parameters of the viscous flow regime were calculated. An influence of nitroplasticizers and dibutyl phthalate on the rheology of nitrocellulose was established. The influence of plasticizers on the mechanical properties of nitrocellulose films was discussed.

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Authors and Affiliations

  1. Research Institute of Polymer Materials, ul. Chistopol’skaya 16, Perm, Russia

    A. E. Golubev

  2. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    A. N. Neshitova, S. A. Kuvshinova, V. A. Burmistrov & O. I. Koifman

  3. Ivanovo Research Institute of Film Materials and Synthetic Leather for Technical Uses, Ivanovo, Russia

    P. V. Singin

  4. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    O. I. Koifman

Authors
  1. A. E. Golubev
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  2. A. N. Neshitova
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  3. P. V. Singin
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  4. S. A. Kuvshinova
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  5. V. A. Burmistrov
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  6. O. I. Koifman
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Corresponding author

Correspondence to A. E. Golubev.

Additional information

Original Russian Text © A.E. Golubev, A.N. Neshitova, P.V. Singin, S.A. Kuvshinova, V.A. Burmistrov, O.I. Koifman, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, No. 5, pp. 33–41.

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Golubev, A.E., Neshitova, A.N., Singin, P.V. et al. Plasticization of Cellulose Nitrate by 4-Nitrophtalic Acid Esters. Russ J Gen Chem 87, 3086–3092 (2017). https://doi.org/10.1134/S107036321712057X

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  • DOI: https://doi.org/10.1134/S107036321712057X

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