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Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 3063–3070 | Cite as

Bifunctionally Substituted Cobalt(II) Phthalocyanines with Benzoic Acid Fragments

  • A. P. Morozova
  • S. A. Znoiko
  • A. S. Vashurin
  • A. V. Zav’yalov
  • V. E. Maizlish
  • G. P. Shaposhnikov
Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)

Abstract

Phthalonitriles with fragments of 4-amino-, 4-hydroxy-, and 4-sulfanylphenylbenzoic acids were synthesized by nucleophilic substitution in 4-bromo-5-nitrophthalonitrile. A disubstituted phthalonitrile containing 1H-1,2,3-benzotriazole and p-hydroxybenzoic acid fragments was obtained by the substitution of the nitro group in 4-(4-carboxyphenoxy)-5-nitrophthalonitrile by a 1H-1,2,3-benzotriazol-1-yl group. The synthesized phthalocyanines were used as starting materials in the template synthesis of bifunctional cobalt phthalocyanines. Spectral properties of the latter products were studied.

Keywords

4-bromo-5-nitrophthalonitrile benzoic acids metal phthalocyanines electronic absorption spectra 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. P. Morozova
    • 1
  • S. A. Znoiko
    • 1
  • A. S. Vashurin
    • 1
  • A. V. Zav’yalov
    • 1
  • V. E. Maizlish
    • 1
  • G. P. Shaposhnikov
    • 1
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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