Skip to main content
Log in

Preparation, Characterization, and Application of Preyssler Heteropoly Acid Immobilized on Magnetic Nanoparticles as a Green and Recoverable Catalyst for the Synthesis of Imidazoles

  • Letters to the Editor
  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

An efficient, magnetically separable catalyst was synthesized by immobilization of Preyssler heteropoly acid (HPA) on Ni0.5Zn0.5Fe2O4 magnetite nanoparticles (MNPs) coated with hydroxyapatite (HA). The catalyst was characterized by scaning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), FT-IR, energy dispersive spectroscopy (EDS), and TGA. Activity of this catalyst was tested in the synthesis of imidazole derivatives via one-pot three-component condensation of [9,10]-phenanthraquinone with aryl aldehydes and ammonium acetate at room temperature under solvent-free conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Rothenberg, G., Catalysis, Weinheim, Germany, Wiley-VCH, 2008.

    Book  Google Scholar 

  2. Sheldon, R.A., Arends, I., and Hanefeld, U., Green Chemistry and Catalysis, Weinheim, Germany, Wiley-VCH, 2007.

    Book  Google Scholar 

  3. Hattori, H., Chem. Rev., 1995, vol. 95, p. 537. doi 10.1021/cr00035a005

    Article  CAS  Google Scholar 

  4. Dong, Z. and Ye, Z., Appl. Catal. A., 2015, vol. 489, p. 61, doi 10.1016/j.apcata.2014.10.009

    Article  CAS  Google Scholar 

  5. Busca, G., Heterogeneous Catalytic Materials, Amsterdam: Elsevier, 2014.

    Google Scholar 

  6. Khojastehnezhad, A., Rahimizadeh, M., Moeinpour, F., Eshghi, H., and Bakavoli, M., Compt. Rend. Chim., 2014, vol. 17, p. 459. doi 10.1016/j.crci.2013.07.013

    Article  CAS  Google Scholar 

  7. Eshghi, H., Khojastehnezhad, A., Moeinpour, F., Bakavoli, M., Seyedi, S.M., and Abbasi. M., RSC Adv., 2014, vol. 4, p. 39782. doi 10.1039/C4RA05133E

    Article  CAS  Google Scholar 

  8. Khojastehnezhad, A., Rahimizadeh, M., Eshghi, H., Moeinpour, F., and Bakavoli, M., Chin. J. Cat., 2014, vol. 35, p. 376. doi10.1016/S1872-2067(14)60001-2

    Article  CAS  Google Scholar 

  9. Goldman, A., Modern Ferrite Technology, New York: Springer, 2006, 2nd ed.

    Google Scholar 

  10. Sheykhan, M., Mamani, L., Ebrahimi, A., and Heydari, A., J. Mol. Catal., 2011, vol. 335, p. 253. doi 10.1016/j.molcata.2010.12.004

    Article  CAS  Google Scholar 

  11. Maleki, B., Barat Nam Chalaki, S., Sedigh Ashrafi, S., Rezaee Seresht, E., Moeinpour, F., Khojastehnezhad, A., and Tayebee, R., Appl. Organometal. Chem., 2015, vol. 29, p. 290. doi 10.1002/aoc.3288

    Article  CAS  Google Scholar 

  12. Moeinpour, F. and Khojastehnezhad, A., Chin. Chem. Lett., 2015, vol. 26, p. 575. doi 10.1016/j.cclet.2015.01.033

    Article  CAS  Google Scholar 

  13. Kim, Y.B., Kim, Y.H., Park, J.Y., and Kim, S.K., Bioorg. Med. Chem. Lett., 2004, vol. 14, p. 541. doi 10.1016/j.bmcl.2003.09.086

    Article  CAS  Google Scholar 

  14. Mashraqui, S.H., Patil, M.B., and Mistry, H.D., Chem. Lett., 2004, vol. 33, p. 1058. doi 10.1246/cl.2004.1058

    Article  CAS  Google Scholar 

  15. Gupta, P., Hameed, S., and Jain, R., Eur. J. Med. Chem., 2004, vol. 39, p. 805. doi 10.1016/j.ejmech.2004.05.005

    Article  CAS  Google Scholar 

  16. Devi, I. and Bhuyan, P.J., Tetrahedron Lett., 2004, vol. 45, p. 8625. doi 10.1016/j.tetlet.2004.09.158

    Article  CAS  Google Scholar 

  17. Mohammadi, M.K., Firuzi, O., Khoshneviszadeh, M., Razzaghi-Asl, N., Sepehri, S., and Miri, R., DARU J. Pharm. Sci., 2014, vol. 22, p. 2. doi 10.1186/2008-2231-22-2

    Article  Google Scholar 

  18. Shelke, K.F., Sapkal, S.B., Kakade, G.K, Shingate, B.B., and Shingare, M.S., Green Chem. Lett. Rev., 2010, vol. 3, p. 27. doi 10.1080/17518250903505246

    Article  CAS  Google Scholar 

  19. Akbari, A., Tetrahedron Lett., 2016, vol. 57, p. 431. doi 10.1016/j.tetlet.2015.12.053

    Article  CAS  Google Scholar 

  20. Kore, R. and Srivastava, R., J. Mol. Catal. A: Chem., 2011, vol. 345, p. 117. doi 10.1016/j.molcata.2011.06.003

    Article  CAS  Google Scholar 

  21. Mirjalili, B.F., Bamoniri, A.H., and Zamani L., Sci. Iran., 2012, vol. 19, p. 565. doi 10.1016/j.scient.2011.12.013

    Article  CAS  Google Scholar 

  22. Safari, J., Dehghan Khalili, Sh., and Banitaba, S.H., Synth. Commun., 2011, vol. 41, p. 2359. doi 10.1080/00397911.2010.502994

    Article  CAS  Google Scholar 

  23. Safari, J., Akbari, Z., and Naseh, S., J. Saudi Chem. Soc., 2016, vol. 20, p. S250. doi 10.1016/j.jscs.2012.10.012

    Article  CAS  Google Scholar 

  24. Damavandi, S. and Sandaroos, R., Arab. J. Chem., 2016, vol. 9, p. S1138. doi 10.1016/j.arabjc.2011.12.004

    Article  CAS  Google Scholar 

  25. Gorsd, M., Sathicq, G., Romanelli, G., Pizzio, L., and Blanco M., J. Mol. Catal. A: Chem., 2016, vol. 420, p. 294. doi 10.1016/j.molcata.2016.04.010

    Article  CAS  Google Scholar 

  26. Liu, E., Xiong, H., Li, L., Yang, Ch., Yin, Zh., Chang, A., Manke, D.R., Golen, J.A., and Zhang, G., Polyhedron, 2017, vol. 127, p. 355. doi 10.1016/j.poly.2017.02.028

    Article  CAS  Google Scholar 

  27. Zare Fekri, L., Nikpassand, M., and Maleki, R., J. Mol. Liq., 2016, vol. 222, p. 77. doi 10.1016/j.molliq.2016.07.009

    Article  Google Scholar 

  28. Kidwai, M., Mothsra, P., Bansal, V., Somvanshi, R.K., Ethayathulla, A.S., Dey, Sh., and Singh T.P., J. Mol. Catal. A: Chem., 2007, vol. 265, p. 177. doi 10.1016/j.molcata.2006.10.009

    Article  CAS  Google Scholar 

  29. Javid, A., Khojastehnezhad, A., Eshghi, H., Moeinpour, F., Bamoharram, F.F., and Ebrahimi, J., Org. Prep. Proc. Int., 2016, vol. 48, p. 377. doi 10.1080/00304948.2016.1206424

    Article  CAS  Google Scholar 

  30. Eshghi, H., Javid, A., Khojastehnezhad, A., Moeinpour, F., Bamoharram, F.F., Bakavoli, M., and Mirzaei, M., Chin. J. Catal., 2015, vol. 36, p. 299. doi 10.1016/S1872-2067(14)60265-5

    Article  CAS  Google Scholar 

  31. Javid, A., Khojastehnezhad, A., Heravi, M.M., and Bamoharram F.F., Synth. React. Inorg. Met.-Org. Chem., 2012, vol. 42, p. 14. doi 10.1080/15533174.2011.609221

    Article  CAS  Google Scholar 

  32. Eshghi, H., Khojastehnezhad, A., Moeinpour, F., Rezaeiana, Sh., Bakavoli, M., Teymouri, M., Rostami, A., and Haghbeen, K., Tetrahedron, 2015, vol. 71, p. 436. doi 10.1016/j.tet.2014.12.010

    Article  CAS  Google Scholar 

  33. Maleki, B., Eshghi, H., Sedigh Ashrafi, S., Khojastehnezhad, A., Esmailian Kahoo, G., Tayebee, R., and Moeinpour, F., RSC Adv., 2015, vol. 5, p. 64850. doi 10.1039/C5RA10534J

    Article  CAS  Google Scholar 

  34. Yousefi Siavashi N., Akhlaghinia, B., and Zarghani, M., Res. Chem. Intermed., 2016, vol. 42, p. 5789. doi 10.1007/s11164-015-2404-8

    Article  Google Scholar 

  35. Gharib, A., Jahangir, M., and Scheeren, J.W., Pol. J. Chem. Technol., 2011, vol. 13, p. 11. doi 10.2478/v10026-011-0017-6

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Javid.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Javid, A., Khojastehnezhad, A. & Pombeiro, A.J.L. Preparation, Characterization, and Application of Preyssler Heteropoly Acid Immobilized on Magnetic Nanoparticles as a Green and Recoverable Catalyst for the Synthesis of Imidazoles. Russ J Gen Chem 87, 3000–3005 (2017). https://doi.org/10.1134/S1070363217120453

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363217120453

Keywords

Navigation