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Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 2986–2988 | Cite as

Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+

  • Xiaoju Liu
  • Yulin Xiang
  • Xiangrong Ma
  • Guoyu Ren
  • Liguo Gao
Letters to the Editor
  • 25 Downloads

Abstract

A probe based on ferrocene structure has been designed, synthesized and elucidated from the single crystal X-ray method. It demonstrated fluorescence response to Hg2+ and Cu2+ in CH3OH. The results indicated that the title complex could be applied in the multianalyte detection. Binding ability of receptor 3 in CH3OH was tested for various cations (Fe3+, Co2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Ba2+ in water). The computed binding constants for Hg2+ and Cu2+ indicated a distinct absorbance shift. The receptor is an attractive array due to its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in biology, environmental sciences and material chemistry.

Keywords

ferrocene ion recognition fluorescence sensor Hg2+ and Cu2+ cation sensing 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Xiaoju Liu
    • 1
  • Yulin Xiang
    • 1
  • Xiangrong Ma
    • 1
  • Guoyu Ren
    • 1
  • Liguo Gao
    • 1
  1. 1.Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering InstituteYu-Lin University of YulinYulin, Shaanxi ProvinceChina

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