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Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 2944–2950 | Cite as

Physicochemical and Spectroscopic Study of Co(II), Ni(II), Cr(III), and Fe(III) Cholyltaurine Adducts

  • F. A. Al-Saif
  • K. A. Alibrahim
  • T. Sharshar
  • M. S. Refat
Letters to the Editor

Abstract

Physical spectroscopic characteristics of Co(II), Ni(II), Cr(III), and Fe(III) cholyltaurine adducts have been studied. IR and Raman spectra confirmed that the cholyltaurine compound acted as a mononegative bidentate chelating agent. Nitrogen atom of the NH group and O of deprotonated sulphonate group acted as chelation sites towards the metal ions. UV-Vis spectra and magnetic moments block measurements confirmed that all complexes had the octahedral geometry. Water, Cl, and NO3 acted as secondary chelates. The positron annihilation lifetime (PAL) technique was applied to investigate the structural changes of cholyltaurine ligand and its complexes. The results indicated that the average defect density in the studied ligand and its complexes was efficiently correlating with their molecular weight.

Keywords

cholyltaurine adducts Raman spectroscopy thermal analysis positron annihilation lifetime spectroscopy 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • F. A. Al-Saif
    • 1
  • K. A. Alibrahim
    • 1
  • T. Sharshar
    • 2
  • M. S. Refat
    • 3
    • 4
  1. 1.Department of ChemistryCollege of Science, Princess Nourah bint Abdulrahman UniversityRiyadhSaudi Arabia
  2. 2.Physics Department, Faculty of ScienceKafrelsheikh UniversityKafr El-SheikhEgypt
  3. 3.Chemistry Department, Faculty of SciencePort Said UniversityPort SaidEgypt
  4. 4.Chemistry Department, Faculty of ScienceTaif UniversityAl-Hawiah, TaifSaudi Arabia

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