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Physicochemical and Spectroscopic Study of Co(II), Ni(II), Cr(III), and Fe(III) Cholyltaurine Adducts

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An Erratum to this article was published on 01 November 2018

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Abstract

Physical spectroscopic characteristics of Co(II), Ni(II), Cr(III), and Fe(III) cholyltaurine adducts have been studied. IR and Raman spectra confirmed that the cholyltaurine compound acted as a mononegative bidentate chelating agent. Nitrogen atom of the NH group and O– of deprotonated sulphonate group acted as chelation sites towards the metal ions. UV-Vis spectra and magnetic moments block measurements confirmed that all complexes had the octahedral geometry. Water, Cl–, and NO3– acted as secondary chelates. The positron annihilation lifetime (PAL) technique was applied to investigate the structural changes of cholyltaurine ligand and its complexes. The results indicated that the average defect density in the studied ligand and its complexes was efficiently correlating with their molecular weight.

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Change history

  • 28 December 2018

    ACKNOWLEDGMENTS should be as follows:

    This work was funded by the Deanship of Scientific Research at “Princess Nourah bint Abdulrahman University,” through the Research Groups Program no. RGP-1438-0001.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia

    F. A. Al-Saif & K. A. Alibrahim

  2. Physics Department, Faculty of Science, Kafrelsheikh University, Kafr El-Sheikh, Egypt

    T. Sharshar

  3. Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt

    M. S. Refat

  4. Chemistry Department, Faculty of Science, Taif University, P.O. Box 888, Al-Hawiah, Taif, 21974, Saudi Arabia

    M. S. Refat

Authors
  1. F. A. Al-Saif
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  2. K. A. Alibrahim
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  3. T. Sharshar
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  4. M. S. Refat
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Correspondence to M. S. Refat.

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Al-Saif, F.A., Alibrahim, K.A., Sharshar, T. et al. Physicochemical and Spectroscopic Study of Co(II), Ni(II), Cr(III), and Fe(III) Cholyltaurine Adducts. Russ J Gen Chem 87, 2944–2950 (2017). https://doi.org/10.1134/S1070363217120362

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