Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 2904–2905 | Cite as

Synthesis of Binuclear Antimony Complexes with Tetraketonate Ligands

  • E. V. Artem’eva
  • O. K. Sharutina
  • V. V. Sharutin
Letters to the Editor
  • 2 Downloads

Abstract

Reactions of tetraphenylantimony bromide with sodium salts of 3,8-dioxodeca-4,6-diene-5,6-diol and 2,2,9,9-tetramethyl-3,8-dioxodeca-4,6-diene-5,6-diol at various molar ratios of the reactants have been studied. Irrespective of the molar ratio, binuclear chelate complexes Ph4Sb[OC(R)CHC(O)(O)CCH(R)CO]SbPh4 are formed. The structures of the resulting complexes were established by the methods of IR and NMR spectroscopy.

Keywords

tetraphenylantimony bromide disodium enolate binuclear complex 

References

  1. 1.
    Handong, Y., Li, Q., and Linwei, L., Inorg. Chem. Commun., 2008, vol. 11, no. 10, p. 1121. doi 10.1016/j.inoche.2008.06.017CrossRefGoogle Scholar
  2. 2.
    De Andrade-Neto, V.F., Goulart, M.O.F., da Silva, F., da Silva, M.J., Pinto, M.C.F.R., Pinto, A.V., Zalis, M.G., Carvalho, L.H., and Krettli, A.U., Bioorg. Med. Chem. Lett., 2004, vol. 14, no. 5, p. 1145. doi 10.1016/j.bmcl.2003.12.069CrossRefGoogle Scholar
  3. 3.
    Bentley, R. and Chasteen, T.G., Microbiol. Mol. Biol. Rev., 2002, vol. 66, no. 2, p. 250. doi 10.1128/MMBR.66.2.250-271.2002CrossRefGoogle Scholar
  4. 4.
    Nomura, R., Yamada, Y., and Matsuda, H., Appl. Organomet. Chem., 1989, vol. 3, no. 4, p. 355. doi 10.1002/aoc.590030410CrossRefGoogle Scholar
  5. 5.
    Igidov, N.M., Koz’minykh, E.N., Sof’ina, O.A., Shironina, T.M., and Koz’minykh, V.O., Chem. Heterocycl. Compd., 1999, vol. 35, no. 11, p. 1276. doi 10.1007/BF02251994CrossRefGoogle Scholar
  6. 6.
    Sharutin, V.V. and Sharutina, O.K., Butlerov Comm., 2014, vol. 38, no. 5, p. 140.Google Scholar
  7. 7.
    Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., and Mukovoz, P.P., Russ. J. Inorg. Chem., 2014, vol. 59, no. 5, p. 508. doi 10.1134/S0036023614050155CrossRefGoogle Scholar
  8. 8.
    Rad, F.K. and Behbahani, F.K., Curr. Org. Synth., 2017, vol. 14, no. 1, p. 22.Google Scholar
  9. 9.
    Klutber, R.W. and Lewis, J.W., J. Am. Chem. Soc., 1960, vol. 82, no. 22, p. 5777. doi 10.1021/ja01507a003CrossRefGoogle Scholar
  10. 10.
    Fukuda, Y., Seino, A., Mafune, K., Nakagawa, H., and Linert, W., J. Coord. Chem., 1994, vol. 33, no. 2, p. 123. doi 10.1080/00958979408024271CrossRefGoogle Scholar
  11. 11.
    Sun, Q., Wang, Q., Shiokawa, Y., and Kawazoe, Y., Chem. Phys. Lett., 2005, vol. 415, nos. 4–6, p. 243. doi 10.1016/j.cplett.2005.09.006CrossRefGoogle Scholar
  12. 12.
    Belousov, Yu.A. and Drozdov, A.A., Russ. Chem. Rev., 2012, vol. 81, no. 12, p. 1159. doi 10.1070/RC2012v081n12ABEH004255CrossRefGoogle Scholar
  13. 13.
    Saalfrank, R.W., Low, N., Demleitner, B., Stalke, D., and Teichert, M., Chem. Eur. J., 1998, vol. 4, no. 7, p. 1305. doi 10.1002/(SICI)1521-3765(19980710) 4:7<1305::AID-CHEM1305>3.0.CO;2-4CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. V. Artem’eva
    • 1
  • O. K. Sharutina
    • 1
  • V. V. Sharutin
    • 1
  1. 1.National Research South Ural State UniversityChelyabinskRussia

Personalised recommendations