Russian Journal of General Chemistry

, Volume 87, Issue 12, pp 2875–2877 | Cite as

Synthesis and Characterization of Barium Amidoborane

  • N. A. Shcherbina
  • I. V. Kazakov
  • A. Yu. Timoshkin
Letters to the Editor
  • 2 Downloads

Abstract

Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.

Keywords

amidoboranes barium NMR spectroscopy IR spectroscopy 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Staubitz, A., Robertson, A.P.M., and Manners, I., Chem. Rev., 2010, vol. 110, no. 7, p. 4079. doi 10.1021/cr100088bCrossRefGoogle Scholar
  2. 2.
    Stennett, T.E. and Harder, S., Chem. Soc. Rev., 2016, vol. 45, no. 4, p. 1112. doi 10.1039/c5cs00544bCrossRefGoogle Scholar
  3. 3.
    Owarzany, R., Leszczyński, P.J. Fijalkowski, K.J., and Grochala, W., Crystals, 2016, vol. 6, no. 5, p. 88. doi 10.3390/cryst6080088CrossRefGoogle Scholar
  4. 4.
    Luo, J., Kang, X., and Wang, P., Energy Environ. Sci., 2013, vol. 6, no. 3, p. 1018. doi 10.1039/C3EE23627GCrossRefGoogle Scholar
  5. 5.
    Wu, H., Zhou W., and Yildirim, T., J. Am. Chem. Soc., 2008, vol. 130, no. 44, p. 14834. doi 10.1021/ja806243fCrossRefGoogle Scholar
  6. 6.
    Zhang, Q., Tang, C., Fang, C., Fan, F., Sun, D., Ouyang, L., and Zhu, M., J. Phys. Chem. (C), 2010, vol. 114, no. 3, p. 1709. doi 10.1021/jp9097233Google Scholar
  7. 7.
    DeGraffenreid, A.L., PhD Thesis, The Ohio State University, Columbus, USA, 1995.Google Scholar
  8. 8.
    Kazakov, I.V., Butlak, A.V, Shelyganov, P.A., Suslonov, V.V., and Timoshkin, A.Y., Polyhedron, 2017, vol. 127, p. 186. doi 10.1016/j.poly.2017.01.062CrossRefGoogle Scholar
  9. 9.
    Kang, X., Ma, L, Fang, Z. Gao, L., Luo, J., Wang, S., and Wang, P., Phys. Chem. Chem. Phys., 2009, vol. 11, p. 2507. doi 10.1039/b820401bCrossRefGoogle Scholar
  10. 10.
    Diyabalanage, H.V.K., Shrestha, R.P., Semelsberger, T.A., Scott, B.L, Bowden, M.E., Davis, B.L., and Burrell, A.K., Angew. Chem. Int. Ed., 2007, vol. 46, p. 8995. doi anie.200702240CrossRefGoogle Scholar
  11. 11.
    Butlak, A.V., Kondrat’ev, Yu.V., and Timoshkin, A.Y., Russ. J. Gen. Chem., 2014, vol. 84, no. 12, p. 2455. doi 10.1134/S1070363214120184CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • N. A. Shcherbina
    • 1
  • I. V. Kazakov
    • 1
  • A. Yu. Timoshkin
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

Personalised recommendations