Abstract
Hydrothermal treatment of aqueous solution of ascorbic acid has resulted in the formation of soluble and insoluble products. The soluble product (carbon quantum dots) has exhibited pronounced fluorescent properties. The insoluble product consists of densely aggregated 1–2 μm particles. The increase in the hydrothermal treatment duration has resulted in continuous transformation of carbon quantum dots into the microparticles.
Similar content being viewed by others
References
Xu, X.Y., Ray, R., Gu, Y.L., Ploehn, H.J., Gearheart, L., Raker, K., and Scrivens, W.A., J. Am. Chem. Soc., 2004, vol. 126, p. 12736. doi 10.1021/ja040082h
Sun, Y.-P., Zhou, B., Lin, Y., Wang, W., Fernando, K.A.S., Pathak, P., Meziani, M.J., Harruff, B.A., Wang, X., Wang, H.F., Luo, P.G., Yang, H., Kose, M.E., Chen, B.L., Veca, L.M., and Xie, S.-Y., J. Am. Chem. Soc., 2006, vol. 128, p. 7756. doi 10.1021/ja062677d
Jelinek, R., Carbon Quantum Dots Synthesis, Properties and Applications, Cham: Springer Int. Publ., 2017. doi 10.1007/978-3-319-43911-2
Lim, S.Y., Shen, W., and Gao, Z., Chem. Soc. Rev., 2015, vol. 44, p. 362. doi 10.1039/C4CS00269E
Zhou, J.G., Booker, C., Li, R.Y., Zhou, X.T., Sham, T.-K., Sun, X.L., and Ding, Z.F., J. Am. Chem. Soc., 2007, vol. 129, p. 744. doi 10.1021/ja0669070
Liu, H.P., Ye, T., and Mao, C.D., Angew. Chem. Int. Ed., 2007, vol. 46, p. 6473. doi 10.1002/anie.200701271
Zhu, H., Wang, X.L., Li, Y.L., Wang, Z.J., Yang, F., and Yang, X.R., Chem. Commun., 2009, vol. 45, p. 5118. doi 10.1039/B907612C
Li, H.T., Ming, H., Liu, Y., Yu, H., He, X.D., Huang, H., Pan, K.M., Kang, Z.H., and Lee, S.-T., New J. Chem., 2011, vol. 35, p. 2666. doi 10.1039/C1NJ20575G
Zhou, J.J., Sheng, Z.H., Han, H.Y., Zou, M.Q., and Li, C.X., Mater. Lett., 2012, vol. 66, p. 222. doi 10.1016/j.matlet.2011.08.081
Feng, X., Zhao, Y., Yan, L., Zhang, Y., He, Y., Yang, Y., and Liu, X., J. Electron. Mater., 2015, vol. 44, p. 3436. doi 10.1007/s11664-015-3893-3
Faisal, N., Liang, W., Long-feng, Z., Xiang-ju, M., and Feng-Shou, X., Chem. Res. Chin. Univ., 2013, vol. 29, no. 3, p. 401. doi 10.1007/s40242-013-2339-9
Liu, D., Qu, F., Zhao, X., and You, J., J. Phys. Chem. (C), 2015, vol. 119, p. 17979. doi 10.1021/acs.jpcc.5b05786
Wang, X., Cheng, J., Yu, H., and Yu, J., Dalton Trans., 2017, vol. 46, p. 6417. doi 10.1039/c7dt00773f
Sun, X.-Y., Wu, L.-L., Shen, J.-S., Cao, X.-G., Wen, C., Liu, B., and Wang, H.-Q., RSC Adv., 2016, vol. 6, p. 97346. doi 10.1039/c6ra19370f
Zhang, B., Liu, C., and Liu, Y., Eur. J. Inorg. Chem., 2010, vol. 2010, p. 4411. doi 10.1002/ejic.201000622
Han, S., Pu, Y.-C., Zheng, L., Hu, L., Zhong Zhang, J., and Fang, X., J. Mater. Chem. (A), 2016, vol. 4, p. 1078. doi 10.1039/c5ta09024e
Mi, Y., Hu, W., Dan, Y., and Liu, Y., Mater. Lett., 2008, vol. 62, p. 1194. doi 10.1016/j.matlet.2007.08.011
Socrates, G., Infrared Characteristic Group Frequencies: Tables and Charts, Toronto: John Wiley & Sons Ltd., 1994.
Hvoslef, J. and Klæboe, P., Acta Chem. Scand., 1971, vol. 25, p. 3043. doi 10.3891/acta.chem.scand.25-3043
Sverdlova, O.V., Elektronnye spektry v organicheskoi khimii (Electronic Spectra in Organic Chemistry), Leningrad: Khimiya, 1985.
Karayannis, M.I., Samios, D.N., and Gousetis, C.P., Anal. Chim. Acta, 1977, vol. 93, p. 275. doi 10.1016/0003-2670(77)80032-9
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.A. Karpushkin, E.S. Kharochkina, A.R. Iarchuk, M.O. Gallyamov, V.G. Sergeyev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 12, pp. 2044–2051.
Rights and permissions
About this article
Cite this article
Karpushkin, E.A., Kharochkina, E.S., Iarchuk, A.R. et al. Hydrothermal Transformations of Ascorbic Acid. Russ J Gen Chem 87, 2858–2864 (2017). https://doi.org/10.1134/S1070363217120167
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363217120167