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Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 151–153 | Cite as

Condensation of СН-acids with cis-1,4-dichlorobut-2-ene

  • G. Z. Raskildina
  • Yu. G. Borisova
  • E. A. Yakovenko
  • L. V. Spirikhin
  • S. S. Zlotskii
Letters to the Editor

Abstract

Synthesis of tri- and five-membered carboxylates are discussed. Microwave irradiation has been shown to stimulate the condensation of СН-acids with allyl chlorides. The selectivity of formation of target products was depending on the CH-acid structure. Structures of the isolated compounds have been confirmed by 1Н and 13С NMR spectroscopy and chromato–mass spectrometry data.

Keywords

СН-acid allyl chloride microwave irradiation gem-disubstituted vinylcyclopropane cyclopentenecarboxylate С-alkylation 

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References

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • G. Z. Raskildina
    • 1
  • Yu. G. Borisova
    • 1
  • E. A. Yakovenko
    • 1
  • L. V. Spirikhin
    • 1
  • S. S. Zlotskii
    • 1
  1. 1.Ufa State Petroleum Technological UniversityUfaRussia

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