Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 145–150 | Cite as

Electrochemical synthesis of conductive polymers based on N-(3-methoxysalicylidene)-o-anisidine and its zinc complexes

  • A. M. Golyakov
  • L. P. Ardasheva
  • A. N. Borisov
Article
  • 34 Downloads

Abstract

Electrochemical oxidation of N-(3-methoxysalicylidene)-o-anisidine and the corresponding Zn(II) complex under potentiodynamic and potentiostatic conditions has resulted in the formation of conductive polymer films on the surface of platinum electrode. Optimal conditions (potential and duration of electrode polarization in a solution of the monomer) of potentiostatic synthesis of polymeric azomethine have been elaborated. Diffusion coefficients of charges and activation energies of charge transfer in the studied polymers are reported.

Keywords

electrochemical polymerization conductive polymer transition metal complex azomethine charge diffusion coefficient 

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References

  1. 1.
    Ardasheva, L.P. and Shagisultanova, G.A., Zh. Neorg. Khim., 1998, vol. 43, no. 1, p. 92.Google Scholar
  2. 2.
    Canali, L., Sherrington, D.C., and Deleuze, H., React. Funct. Polym., 1999, vol. 40, no. 2, p. 155. doi 10.1016/S1381-5148(98)00045-5CrossRefGoogle Scholar
  3. 3.
    Revenga-Parra, M., Lorenzo, E., and Pariente, F., Sensors and Actuators (B), 2005, vol. 107, no. 2, p. 678. doi 10.1016/j.snb.2004.11.053.CrossRefGoogle Scholar
  4. 4.
    Shahrokhian, S. and Fotouhi, L., Sensors and Actuators (B), 2007, vol. 123, no. 2, p. 942. doi 10.1016/j.snb.2006.10.053CrossRefGoogle Scholar
  5. 5.
    Shagisultanova, G.A., Theor. Eksp. Khim., 1991, vol. 3, p. 330.Google Scholar
  6. 6.
    Vilas-Boas, M., Santos, I.C., Henderson, M.J., Freire, C., Hillman, A.R., and Vieil, E., Langmuir., 2003, vol. 19, no. 18, p. 7460. doi 10.1021/la034525rCrossRefGoogle Scholar
  7. 7.
    Shagisultanova, G.A., Orlova, I.A., and Borisov, A.N., Photochem. Photobiol. (A), 1997, vol. 103, no. 3, p. 249. doi 10.1016/S1010-6030(96)04476-0CrossRefGoogle Scholar
  8. 8.
    Golyakov, A.M., Cand. Sci. (Chem.) Dissertation, St. Petersburg, 2013.Google Scholar
  9. 9.
    Hoferkamp, L.A. and Goldsby, K.A., Chem. Mater., 1989, vol. 1, no. 3, p. 348. doi 10.1021/cm00003a015.CrossRefGoogle Scholar
  10. 10.
    Blaho, J.K., Hoferkamp, L.A., and Goldsby, K.A., Polyhedron, 1989, vol. 8, no. 1, p. 113. doi 10.1016/S0277-5387(00)86388-3CrossRefGoogle Scholar
  11. 11.
    Reutov, O.A., Kurts, A.L., and Butin, K.P., Organicheskaya khimiya (Organic Chemistry), Moscow: Binom, 2004, ch. 3.Google Scholar
  12. 12.
    Vilas-Boas, M., Freire, C., de Castro, B., and Hillman, A.R., J. Phys. Chem. (B), 1998, vol. 102, no. 43, p. 8533. doi 10.1021/jp982160rCrossRefGoogle Scholar
  13. 13.
    Kaufmann, F.B., Shroeder, A.H., Engler, E.M., Kramer, S.R., and Chambers, J.Q., J. Am. Chem. Soc., 1980, vol. 102, no. 2, p. 483. doi 10.1021/ja00522a007CrossRefGoogle Scholar
  14. 14.
    Plambeck, J.A., Electroanalytical Chemistry: Basic Principles and Applications, New York: Wiley, 1980, ch. 17.Google Scholar
  15. 15.
    Leidner, C.R. and Murray, R.W., J. Am. Chem. Soc., 1985, vol. 107, no. 3, p. 551. doi 10.1021/ja00289a005.CrossRefGoogle Scholar
  16. 16.
    Pak, V.N. and Stromova, E.S., Russ. J. Appl. Chem., 2007, vol. 80, no. 2, p. 221. doi 10.1134/S1070427207020103CrossRefGoogle Scholar
  17. 17.
    Puzyk, M.V., Baichurin, R.I., and Borisov, A.N., Optics and Spectroscopy, 2016, vol. 120, no. 3, p. 386. doi 10.1134/S0030400X16030188CrossRefGoogle Scholar
  18. 18.
    Nakasini, K., Infrared Spectra and Structure of Organic Compounds, Moscow Mir, 1965.Google Scholar
  19. 19.
    Mayo, D.W., Course Notes on the Interpretation of Infrared and Raman Spectra, New Jersey John Willey & Sons. Inc., 2003.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. M. Golyakov
    • 1
  • L. P. Ardasheva
    • 1
  • A. N. Borisov
    • 1
  1. 1.Herzen Russian State Pedagogical UniversitySt. PetersburgRussia

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