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Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 139–144 | Cite as

Synthesis of polymers containing polyaniline fragments linked by 1,4-benzoquinone groups

  • A. A. Durgaryan
  • R. A. Arakelyan
  • N. A. Durgaryan
Article

Abstract

Michael reaction of 1,4-benzoquinone and N-acetyl-4,4'-diaminodiphenylamine has afforded a new polymer; hydrolysis of the latter has yielded a product containing polyaniline fragments connected by 1,4- benzoquinone units in the backbone. The interaction of 1,4-benzoquinone and 1,4-phenylenediamine has afforded an earlier described polymer that has been characterized by IR and UV spectroscopy. 2,5-Bis[(4-aminophenyl)amino]-1,4-benzoquinone prepared from the mentioned compounds at a 3: 2 molar ratio under the same reaction conditions, can exist in three tautomeric forms. Electroconductivity of the prepared polymers increases from <10–10 to 10–6 S/cm with the doping level increase.

Keywords

polycondensation aniline oligomer electron absorption spectroscopy NMR spectroscopy 1,4-benzoquinone Michael reaction 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. A. Durgaryan
    • 1
  • R. A. Arakelyan
    • 1
  • N. A. Durgaryan
    • 1
  1. 1.Yerevan State UniversityYerevanArmenia

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