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Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 122–127 | Cite as

Synthesis and structure of the palladium complexes [Ph3P(CH2)3PPh3][PdBr4], [Ph3P(CH2)3PPh3][Pd2Br6]·DMF, and [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2

  • V. V. Sharutin
  • O. K. Sharutina
  • V. S. Senchurin
  • I. A. Il’chenko
  • P. V. Andreev
Article

Abstract

Complexes [Ph3P(CH2)3PPh3][PdBr4] and [Ph3P(CH2)3PPh3][Pd2Br6]·DMF were synthesized by the reaction of dihydrogentetrabromopalladic acid with trimethylenebis(triphenylphosphonium) dibromide in water with subsequent recrystallization from N,N-dimethylformamide. The recrystallization of the first of them from dimethyl sulfoxide leads to the formation of the complex [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2. Structure of the complexes was investigated by the X-ray diffraction (XRD) analysis.

Keywords

bromopalladate(II) anions trimethylenebis(triphenylphosphonium) cation N,N-dimethylformamide dimethyl sulfoxide X-ray diffraction analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • V. V. Sharutin
    • 1
  • O. K. Sharutina
    • 1
  • V. S. Senchurin
    • 1
  • I. A. Il’chenko
    • 1
  • P. V. Andreev
    • 2
  1. 1.National Research South Ural State UniversityChelyabinskRussia
  2. 2.National Research Nizhny Novgorod State UniversityNizhny NovgorodRussia

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