Advertisement

Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 29–32 | Cite as

Alkylation of 1-(prop-2-ynyl)piperidine with СН-acids in ihe presence of mercury(II) acetate

  • N. G. Hobosyan
  • K. V. Balyan
  • A. L. Petrosyan
  • S. A. Hovakimyan
  • Zh. A. Chobanyan
  • R. S. Nersisyan
Article
  • 35 Downloads

Abstract

General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl)piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1-ynyl]mercury. Conditions of these reactions were optimized.

Keywords

alkylationе acetylacetone acetoacetic ester prototropic isomers 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Badanyan, Sh.O., Chobanyan, Zh.A., Tirakyan, M.R., and Danielyan, A.O., Chem. Heterocycl. Compd., 1998, vol. 34, no. 7, p. 781. doi 10.1007/BF02251682CrossRefGoogle Scholar
  2. 2.
    Hobosyan, N.G., Balyan, K.V., Nersisyan, H.S., Sargsyan, H.B, Chobanyan, Zh.A., Russ. J. Gen. Chem., 2016, vol. 86, p. 1011. doi 10.1134/S1070363216050042CrossRefGoogle Scholar
  3. 3.
    Balyan, K.V., Gendzhoyan, L.M., Akopyan, B.B., Hobosyan, N.G., and Chobanyan, Zh.A., Russ. J. Gen. Chem., 2014, vol. 84, no. 11, p. 2098. doi 10.1134/S1070363214110097CrossRefGoogle Scholar
  4. 4.
    Müller, T.E., Hultzsch, K.C., Yus, M., Foubelo, F., and Tada, M., Chem. Rev., 2008, vol. 108, no. 9, p. 3795. doi 10.1021/cr0306788CrossRefGoogle Scholar
  5. 5.
    Fäcke, T. and Berger, S., J. Organomet. Chem., 1994, vol. 471, nos. 1–2, p. 35. doi 10.1016/0022-328X(94) 88102-2CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • N. G. Hobosyan
    • 1
    • 2
  • K. V. Balyan
    • 1
  • A. L. Petrosyan
    • 1
  • S. A. Hovakimyan
    • 2
  • Zh. A. Chobanyan
    • 1
  • R. S. Nersisyan
    • 1
  1. 1.Institute of Organic Chemistry, Research and Technology Center of Organic and Pharmaceutical ChemistryNational Academy of Sciences of ArmeniaYerevanArmenia
  2. 2.Аbobyan Armenian State Pedagogical UniversityYerevanArmenia

Personalised recommendations