Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 13–15 | Cite as

Synthesis of bicyclic diesters of malonic and succinic acids

  • M. K. Mamedov
  • F. S. Kerimova
  • J. G. Ismailova
Article
  • 39 Downloads

Abstract

Monoesters of malonic and succinic acids have been prepared in high yields by the BF3·OEt2-catalyzed addition of the acids to bicyclo[2.2.1]hept-2-ene. The synthesized monoesters were introduced in the reaction of esterification with saturated monoatomic alcohols С2–С7 in the presence of the KU-2-8 catalyst in the H-form, and the corresponding mixed diesters of dicarboxylic acids were obtained in high yields.

Keywords

bicyclo[2.2.1]hept-2-ene malonic and succinic acids norbornene monoatomic alcohols diesters of dicarboxylic acids 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • M. K. Mamedov
    • 1
  • F. S. Kerimova
    • 1
  • J. G. Ismailova
    • 1
  1. 1.Yu.G. Mamedaliev Institute of Petrochemical ProcessesAzerbaidjan Academy of SciencesBakuAzerbaijan

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