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Synthesis of bicyclic diesters of malonic and succinic acids

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Abstract

Monoesters of malonic and succinic acids have been prepared in high yields by the BF3·OEt2-catalyzed addition of the acids to bicyclo[2.2.1]hept-2-ene. The synthesized monoesters were introduced in the reaction of esterification with saturated monoatomic alcohols С2–С7 in the presence of the KU-2-8 catalyst in the H-form, and the corresponding mixed diesters of dicarboxylic acids were obtained in high yields.

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Correspondence to M. K. Mamedov.

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Original Russian Text © М.K. Mamedov, F.S. Kerimova, J.G. Ismailova, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 1, pp. 17–19.

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Mamedov, M.K., Kerimova, F.S. & Ismailova, J.G. Synthesis of bicyclic diesters of malonic and succinic acids. Russ J Gen Chem 87, 13–15 (2017). https://doi.org/10.1134/S1070363217010030

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  • DOI: https://doi.org/10.1134/S1070363217010030

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