Synthesis of bicyclic diesters of malonic and succinic acids
- 39 Downloads
Monoesters of malonic and succinic acids have been prepared in high yields by the BF3·OEt2-catalyzed addition of the acids to bicyclo[2.2.1]hept-2-ene. The synthesized monoesters were introduced in the reaction of esterification with saturated monoatomic alcohols С2–С7 in the presence of the KU-2-8 catalyst in the H-form, and the corresponding mixed diesters of dicarboxylic acids were obtained in high yields.
Keywordsbicyclo[2.2.1]hept-2-ene malonic and succinic acids norbornene monoatomic alcohols diesters of dicarboxylic acids
Unable to display preview. Download preview PDF.
- 1.Mamedov, M.K., Proc. Petrochem. Oil Ref., 2001, no. 1(7), p. 38.Google Scholar
- 3.Mamedov, M.K. and Suleimanova, E.E., Zh. Org. Khim., 1993, vol. 29, no. 6, p. 1138.Google Scholar
- 4.Suleimanova, E.A. and Gashimov, Kh.A., Author’s Cerificate 1415687, 1986.Google Scholar
- 5.Suleimanova, E.E. and Mamedov, M.K., Azerb. Neft. Khoz., 1994, no. 5, p. 51.Google Scholar